Radicals as Chiral Catalysts for Asymmetric Radical Cyclization Reactions

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外文摘要：Due to the innate highly reactive properties and short life-time,organic free radicals can often serve as promoters or intermediates to engage in various radical transformations,which are often otherwise difficult to access by ionic pathway-based mechanisms.With the evolvement of radical chemistry,chiral radical catalyzed-transformations have recently emerged as an attractive and robust plat-form for synthesis of chiral molecules of interest.Herein,we highlight several creative and strategic advances in chiral radical catalyst design,cyclization reaction achievements,and future challenges.

外文关键词：

Chiral radical catalysisRadical cyclizationThiyl radicalBoryl radicalAsymmetric synthesis

作者：

Quan-Qing Zhao、Min Gu、Jia-Rong Chen

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作者单位：

Jiangsu Key Laboratory of Marine Pharmaceutical Compound Screening,College of Pharmacy,Jiangsu Ocean University,Lianyungang,Jiangsu 222005,China

Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction,College of Chemistry,Central China Normal University,Wuhan,Hubei 430079,China

出版年：

2024

DOI：

10.1002/cjoc.202400349

中国化学(英文版)

中国化学会上海有机化学研究所

中国化学(英文版)

CSTPCD

影响因子：0.848

ISSN：1001-604X

年,卷(期)：2024.42(19)