Emergent Physics in Metal-Organic Frameworks

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外文摘要：Many-body interactions in condensed matter could lead to emergent phenomena spanning superconductivity,ferromagnetism,ex-citon condensation,etc.The emergence of these phenomena often requires highly ordered spatial arrangements of the interacting species to enforce specific space symmetries and interacting strengths.Metal-organic frameworks(MOFs),crystalline materials formed by self-assembly of metal ions and organic ligands,allow for precise design of their crystal structures and sophisticated tun-ing of Coulombic interaction or magnetic coupling among lattice sites.Such atomic-level designability combined with high crystallin-ity and versatile types of lattices(e.g.,kagome and honeycomb lattices)render MOFs as a great platform to investigate emergent physics.In this Emerging Topic,we summarize recent studies evidencing emergent phenomena in MOFs including strong correla-tions,superconductivity,charge density wave,long-range magnetic order,and quantum spin liquid.We highlight the great potential of MOFs as quantum materials and discuss challenges including growth of high-quality single crystals and in-depth physical charac-terizations to reveal insights into the nature of physical properties of MOFs.

外文关键词：

Metal-organic frameworksEmergent physicsStrong correlationsSuperconductorsMagnetic properties

作者：

Shaoze Wang、Yingchao Wang、Haozhou Sun、Lei Sun

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作者单位：

Department of Chemistry,School of Science and Research Center for Industries of the Future,Westlake University,600 Dunyu Road,Hangzhou,Zhejiang 310030,China

Key Laboratory for Quantum Materials of Zhejiang Province,Department of Physics,School of Science,Westlake University,600 Dunyu Road,Hangzhou,Zhejiang 310030,China

Institute of Natural Sciences,Westlake Institute for Advanced Study,18 Shilongshan Road,Hangzhou,Zhejiang 310024,China

出版年：

2024

DOI：

10.1002/cjoc.202400272

中国化学(英文版)

中国化学会上海有机化学研究所

中国化学(英文版)

CSTPCD

影响因子：0.848

ISSN：1001-604X

年,卷(期)：2024.42(20)