Rhodium-Catalyzed C(sp3)-H Arylation of 8-Methylquinolines with Arylsilanes

扫码查看

原文链接

万方数据

外文摘要：We herein describe a Cp*RhⅢ-catalyzed C(sp3)-H mono-arylation of 8-methylquinolines with benign arylsilanes.The use of 1-adamantane carboxylic acid can benefit the efficiency in this transformation,and AgF was both activator and reoxidant.Control ex-periments indicated inability of C-H cleavage in determining the rate of the reaction.

外文关键词：

C(sp3)-H arylationC-H activationArylsilanesCross-couplingNitrogen heterocycles

作者：

Lin Li、Haidong Liu、Yupeng Qian、Guohong Shen、Yun Shi、Jiajie Du、Haiqing Luo

展开 >

作者单位：

Department of Chemistry&Chemical Engineering,Gannan Normal Univeristy,Ganzhou,Jiangxi 341000,China

出版年：

2024

DOI：

10.1002/cjoc.202400429

中国化学(英文版)

中国化学会上海有机化学研究所

中国化学(英文版)

CSTPCD

影响因子：0.848

ISSN：1001-604X

年,卷(期)：2024.42(21)