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Skeletal Editing of Cyclic Molecules Using Nitrenes

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Nitrenes,as neutral monovalent nitrogen-centered molecular species,can insert into various bond or remove nitrogen atoms from amines.Nitrene assisted single-atom skeletal editing,discovered decades ago,provides an efficient approach for the precise alteration of cyclic skeletons.In this review,we briefly summarize early studies on skeletal editing of cyclic frameworks involving nitrene species,and introduce several recent important advances systematically.

NitrenesSkeletal EditingCyclic CompoundsAtom exchangeLate-stage modification

Yi-An Xu、Shao-Hua Xiang、Jin-Teng Che、Yong-Bin Wang、Bin Tan

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Shenzhen Grubbs Institute,Department of Chemistry,Southern University of Science and Technology,Shenzhen,Guangdong 518055,China

2024

中国化学(英文版)
中国化学会 上海有机化学研究所

中国化学(英文版)

CSTPCD
影响因子:0.848
ISSN:1001-604X
年,卷(期):2024.42(21)