首页|Multiple Interaction Forces Construct Two-Dimensional Self-assembly Kagome Lattices on Au(111)

Multiple Interaction Forces Construct Two-Dimensional Self-assembly Kagome Lattices on Au(111)

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Kagome lattices have garnered significant attention due to their promising applications in catalysis,electronics,and magnetics.Alt-hough many efforts have been paid to the design and synthesis of Kagome lattices,there is a limited focus on constructing this lattice by multiple interaction forces.In this work,we employ 2,7-dibromo-carbazole as precursors to successfully fabricate the two-dimen-sional self-assembly Kagome lattices stabled by multiple interaction forces on Au(111)substrate.Using low-temperature scanning tunneling microscopy,non-contact atomic force microscopy and density functional theory calculation,we visualize and identify the four interaction forces within Kagome lattices:Au—N coordination bonds,Au—H hydrogen bonds,Br—Br halogen bonds,and Br—H hydrogen bonds,respectively.This study provides a basic understanding for designing and constructing more complex Kagome lattices.

Kagome latticesScanning tunneling microscopyNon-contact atomic force microscopyInteraction forcesSupramolecular networksHalogen bondingMolecular evolutionSelf-assembly

Yong Zhang、Jianchen Lu、Wuyi Gao、Yi Zhang、Nianqiang Li、Shicheng Li、Gefei Niu、Boyu Fu、Lei Gao、Jinming Cai

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Faculty of Materials Science and Engineering,Kunming University of Science and Technology,Kunming,Yunnan 650093,China

Faculty of Science,Kunming University of Science and Technology,Kunming,Yunnan 650500,China

Southwest United Graduate School,Kunming,Yunnan 650093,China

2024

中国化学(英文版)
中国化学会 上海有机化学研究所

中国化学(英文版)

CSTPCD
影响因子:0.848
ISSN:1001-604X
年,卷(期):2024.42(22)