首页|Vinylogous Fluorine Stabilizing Effect Enables Rational Design of a Novel Donor-Acceptor Cyclopropane and Its Applications in[3+2]Cycloaddition Reaction and Ring-Opening Polymerization
Vinylogous Fluorine Stabilizing Effect Enables Rational Design of a Novel Donor-Acceptor Cyclopropane and Its Applications in[3+2]Cycloaddition Reaction and Ring-Opening Polymerization
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
万方数据
维普
Discovery of unprecedented donor-acceptor patterns can essentially enrich the chemistry of donor-acceptor cyclopropanes.We here-in introduce a concept of vinylogous fluorine stabilizing effect,which guides rational design of a novel donor-acceptor cyclopropane employing gem-difluorovinyl group as the electron donor,namely dFVCP.Application of such dFVCPs in a[3+2]cycloaddition with al-dehydes and a controlled ring-opening polymerization by a Mg(OTf)2/DIPEA/C(sp3)-H initiator system have been demonstrated,providing direct access to fluorine-containing tetrahydrofurans and all-carbon main-chain polymers.
Hefei National Research Center for Physical Sciences at the Microscale and Department of Polymer Science and Engineering,University of Science and Technology of China,Hefei,Anhui 230026,China
万方数据
维普
