A General Electron Donor-Acceptor Photoactivation Using Oxime Esters Enabled Divergent Thioetherifications

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外文摘要：The EDA complex-mediated reactions involving oxime esters have been few studied.Herein,an EDA complex formed by thiophenolate anion and oxime ester is reported for photoinduced divergent synthesis of thioethers,depending on different types of oxime esters.Operational simplicity,mild reaction conditions,and flexible options of leaving group demonstrate the generality and synthetic utility of this approach.Such an approach can also enable an interesting thiol-catalysis for the synthesis of phenanthridines.

外文关键词：

PhotochemistryEDA complexThioetherificationOxime esterThiol-catalysisOrganosulfursRadical reactionsCross-couplingMethodology and reactions

作者：

Maojian Lu、Liang-Liang Jiang、Yue-Ming Xu、Sanliang Li、Qing-Xiao Tong、Jian-Ji Zhong

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作者单位：

College of Chemistry and Chemical Engineering,and Key(Guangdong-Hong Kong Joint)Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province,Shantou University,Shantou,Guangdong 515063,China

Chemistry and Chemical Engineering Guangdong Laboratory,Shantou,Guangdong 515063,China

出版年：

2024

DOI：

10.1002/cjoc.202400564

中国化学(英文版)

中国化学会上海有机化学研究所

中国化学(英文版)

CSTPCD

影响因子：0.848

ISSN：1001-604X

年,卷(期)：2024.42(22)