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Functionalization of Boranes through Thiol/Oxygen Catalysis+

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A greener and more convenient alternative to traditional methods for the generation of thiyl radical as hydrogen atom transfer(HAT)catalyst is developed,using molecular oxygen to oxidize thiol without the need for chemical initiators or light irradiation.The thi-ol/oxygen catalysis enables selective and efficient difunctionalization of borane.

BoranesThiyl radicalOxygenBorane difunctionalizationSynthetic methodsGreen chemistry

Hongyi Tao、Hairong Lyu

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Department of Chemistry,The Chinese University of Hong Kong,Shatin,N.T.,Hong Kong SAR,China

2024

中国化学(英文版)
中国化学会 上海有机化学研究所

中国化学(英文版)

CSTPCD
影响因子:0.848
ISSN:1001-604X
年,卷(期):2024.42(22)