Metal-Decorated Porous Organic Polymers:Bridged the Gap between Organic and Inorganic Scaffolds

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外文摘要：Advanced functionalization-decorated porous organic polymers(POPs)are emerging as a prominent research focus,spanning from their construction to applications in gas storage and separation,catalysis,energy storage,electrochemistry,and other areas.Further-more,the inherent organic nature,tailored pore structures,and adjustable chemical components of POPs offer a versatile platform for the incorporation of various metal active sites.Meticulously designed molecular building blocks can serve as organic ligands uniformly distributed throughout POPs,leading to the effective isolation of inorganic metal active sites at the molecular level.In this manner,POPs containing active metal centers bridge the gap between organic and inorganic scaffolds.This review aims to provide an overview of recent research progress on metal-decorated POPs,focusing on strategies for incorporating metal active sites into POPs and their applications in adsorption,separation,catalysis,and photoelectrochemistry.Finally,current challenges and future prospects are dis-cussed for further research.

外文关键词：

Porous polymersMetal functionalizationAdsorptionCatalysisActive sitesFunctional polymers

作者：

Zhu Gao、Yufei Liu、Shaofei Wu、Juntao Tang、Kuanyu Yuan、Chunyue Pan、Guipeng Yu

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作者单位：

College of Chemistry and Chemical Engineering,Central 5outh University,Changsha,Hunan 410083,China

Department of Chemistry,National University of Singapore,3 Science Drive 3,117543,Singapore

School of Chemistry,Chemical Engineering and Materials,Jining University,Qufu,Shandong 273100,China

出版年：

2024

DOI：

10.1002/cjoc.202400386

中国化学(英文版)

中国化学会上海有机化学研究所

中国化学(英文版)

CSTPCD

影响因子：0.848

ISSN：1001-604X

年,卷(期)：2024.42(22)