首页|Advances on Theory and Experiments of the Energy Applications in Graphdiyne

Advances on Theory and Experiments of the Energy Applications in Graphdiyne

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After years of development,graphdiyne(GDY)has demonstrated the characteristics of transformative materials in many fields and has promoted great progress in fundamental and applied research.In practice,some important new concepts have been proposed,such as natural surface charge distribution inhomogeneity,multicavity space limiting effect,in-complete charge transfer effect on the atomic level,alkyne-alkene conversion of a chemical bond,in situ induction of constrained growth,reversible transition from high to low valence state,and so on.These characteristics originating from the special electron-ic structure and chemical structure of GDY have rapidly promoted the development of GDY science in recent years and produced many exciting results in fundamental and applied science.Therefore,we sys-tematically introduce the recent theoretical and ex-perimental progress of GDY in terms of its new structural,electronic,mechanical,thermal,and opti-cal properties and its promising applications in the energy fields of membrane sciences,catalysis,ener-gy storage,and conversion.Specifically,the great breakthrough of GDY zero-valence atomic catalysts,quantum dots catalysts,and heterostructure cata-lysts for catalytic applications are discussed in detail.We believe this review will provide some significant guidelines for the design and development of GDY-based high-performance materials and devices in energy fields.

graphdiyneenergy applicationsexperi-mental advancestheoretical insights

Feng He、Yuliang Li

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CAS Key Laboratory of Organic Solids,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190

School of Chemical Sciences,University of Chinese Academy of Sciences,Beijing 100049

国家自然科学基金国家自然科学基金国家自然科学基金国家重点研发计划

2179005021790051220053102018YFA0703501

2023

中国化学会会刊(英文)

中国化学会会刊(英文)

CSCD
ISSN:
年,卷(期):2023.5(1)
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