首页|激光定向能量沉积Inconel 718合金高频窄脉冲电化学后处理行为研究

激光定向能量沉积Inconel 718合金高频窄脉冲电化学后处理行为研究

扫码查看
高频窄脉冲电解加工技术能有效提高加工精度和表面质量,在镍基高温合金等难加工金属材料的精密制造方面有着广泛的应用.然而,对于微观组织极不均匀的激光定向能量沉积构件,其加工质量尚不清晰,尤其是采用无水电解液时.以激光定向能量沉积Inconel 718合金为研究对象,采用频率为30~100 kHz、占空比为30%~80%的高频窄脉冲电流以及饱和NaCl乙二醇电解液进行射流电解加工实验.结果表明:沉积态Inconel 718合金组织由γ基体相、Nb偏析区与枝晶间相(主要为γ/Laves共晶相)组成;在10.50 A/cm2的电流密度下,加工区表面粗糙度随脉冲频率的增加而增大,且脉冲频率为30 kHz时表面粗糙度最小(Ra=1.562 μm),加工精度最高;表面粗糙度随占空比的增加先减小后增大,占空比为50%时表面粗糙度最小,占空比为60%时加工精度最高;而在直流模式下,表面粗糙度随电流密度的增大而降低,且电流密度为10.50 A/cm2时,表面质量最优(Ra=0.526 μm),这是由于高电流密度更容易诱导表面"过饱和盐膜"的形成,从而有效抑制选择性溶解,降低表面粗糙度.但在加T精度方面,高频窄脉冲电流模式的加工定域性较好.最后,基于"盐膜"理论和双电层模型,揭示了高频窄脉冲电流模式下沉积态Inconel 718合金的微区阳极溶解机理,为提高激光增材制造镍基高温合金射流电解加工表面质量提供了理论支撑和实验依据.
Study on High-Frequency Narrow Pulse Electrochemical Post-Processing Behavior of Inconel 718 Alloy by Laser Directed Energy Deposition
Objective Laser-directed energy deposition(LDED)is an effective technique for processing Inconel 718.However,because of the overlap of cladding tracks and the stacking effect of the deposition layers with unmelted powders,the processing accuracy and surface quality of the as-deposited parts are poor;thus,subsequent substrate processing must be performed before use.Electrochemical machining(ECM)can effectively improve machining accuracy and surface quality and has a wide range of applications in the precision manufacturing of difficult-to-process metals(such as nickel-based superalloys).Therefore,ECM is used for the subsequent substrate processing of LDED-Inconel 718 components.However,the processing quality of LDED components with inhomogeneous microstructures is unclear,particularly when nonwater-based electrolytes are used.Therefore,the microstructural characteristics and dissolution behavior of the constituent phases of the LDED-Inconel 718 alloy under a pulsed current and ethylene glycol electrolyte are systematically investigated to improve the surface quality of the LDED-Inconel 718 alloy.Methods In this study,the LDED-Inconel 718 alloy is used as the research object.The parameters of the high-frequency narrow-pulse current with a frequency of 30-100 kHz,duty cycle of 30%-80%,and saturated NaCl glycol electrolyte are employed to perform electrolyte jet machining(EJM)experiments.The dendritic morphologies and constituent phases of the as-deposited Inconel 718 alloy and the micro-morphologies of the machined surface after the EJM experiments are characterized using scanning electron microscope(SEM).Confocal laser microscope is performed to measure the central region of the groove along the X-axis.The surface-machining quality of the groove is characterized based on the surface roughness,and the machining precision is evaluated based on the depth-to-width ratio of the groove profile.Results and Discussions The results show that the microstructure of the as-deposited Inconel 718 alloy is composed of the γmatrix phase,Nb-segregated y phase,and inter-dendritic phase(mainly the γ/Laves eutectic phase),as shown in Fig.2.At a current density of 10.50 A/cm2,the surface roughness increases with increasing pulse frequency,and the smallest surface roughness(Ra=1.562 μm)and highest machining accuracy(Fig.5)are obtained when the pulse frequency is 30 kHz.The surface roughness first decreases and then increases with an increase in the duty cycle,whereas the machining precision is optimum when the duty cycle is 60%(Fig.7).In the direct-current mode,the surface roughness decreases with increasing current density.When the current density reaches 10.50 A/cm2,the surface quality is the best(Ra=0.526 μm).This is because a high current density can easily induce the formation of surface-supersaturated salt films and effectively inhibit selective dissolution and reduce the surface roughness.However,in terms of the machining accuracy,the processing localization in the high-frequency narrow pulse mode is better(Fig.9).Conclusions Two stages(transpassivation dissolution and salt film leveling stages)exist during the direct-current mode EJM process.During the first stage,the composition and structure of the transpassivation films on the surface of the Inconel 718 alloy result in a dissolution rate difference.During the second stage,the salt films on the Inconel 718 surface eliminate the difference in the dissolution rate of each phase,and a smooth surface is formed.In the pulse current model,the dissolution process is divided into transpassive dissolution,salt film leveling,and salt film vanishing stages.However,the surface quality of the alloy is poor because of the periodic on-off property of the pulse current.The current density around the edge of the groove is very low owing to the pulse current characteristics;thus,the transpassive film is difficult to break,which improves the machining accuracy.

laser techniquelaser directed energy depositionInconel 718 nickel based superalloyelectrolyte jet machiningsurface integritymachining precision

耿建峰、吴琳、郭鹏飞、王慧君、林鑫、张宇锋、杨光、黄卫东

展开 >

青岛理工大学山东增材制造工程技术研究中心,山东青岛 266520

西北工业大学凝固技术国家重点实验室,陕西西安 710072

沈阳航空航天大学机电工程学院,辽宁沈阳 110136

激光技术 激光定向能量沉积 Inconel 718镍基高温合金 射流电解加工 表面完整性 加工精度

国家自然科学基金国家自然科学基金山东省自然科学基金

52005280U22A20189ZR2020ZDD04

2024

中国激光
中国光学学会 中科院上海光机所

中国激光

CSTPCD北大核心
影响因子:2.204
ISSN:0258-7025
年,卷(期):2024.51(10)
  • 6