首页|Efficient synthesis of forsterite via high-temperature thermochemical reactions from boron mud waste without briquetting
Efficient synthesis of forsterite via high-temperature thermochemical reactions from boron mud waste without briquetting
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Forsterite is a highly demanded material in high-temperature industries due to its superior performance in elevated temperatures.This study proposes synthesizing high-quality forsterite via high-temperature thermochemical reactions using abundant boron mud waste.The new synthesis method capitalizes on the high reactivity of fine raw powder materials,enabling the reaction to reach completion at low temperatures rapidly.The chemical characteristics,microscopic morphology,and structure of synthe-sized samples are systematically studied using XRD and SEM.The results confirm that boron mud can be efficiently transformed into forsterite after 10 min of reactions at 1500 ℃.The synthesized products attain over 98.7%densification and contain more than 85.0%forsterite with well-developed grains.The activation energy of forsterite grain growth in the 1100-1500 ℃ temperature range is 165.5 kJ/mol.This study provides a low-cost method for producing forsterite and an efficient and environmentally friendly solution for treating solid waste.
Fluidized bedBoron mudForsteriteSolid state reactionActivation energyGrain growth
Fangling Hu、Liangliang Fu、Qingjin Zhang、Guangwen Xu、Dingrong Bai
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Key Laboratory on Resources Chemicals and Material of Ministry of Education,Shenyang University of Chemical Technology,Shenyang,110142,China
School of Chemical Engineering,University of Science and Technology Liaoning,Anshan,114051,China
School of Materials Science and Engineering,Shenyang University of Technology,Shenyang,110142,China