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物理化学的统一性及其尺度效应

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"玻璃态物质的本质是什么?"在2005年被列为未来25年最主要的科学难题之一。本文从跨尺度力学的角度发现玻璃态物质的玻璃化转变源于标度律(临界跃迁、或跨尺度效应),是分子物理与凝聚态物理临界转变的非连续和非平衡态跃迁。(1)玻璃化转变是"有序(排列概率分布)-无序(组合概率分布)"转变,也是相分离-微相分离转变;(2)玻璃化转变具有协同效应,其"分子纠缠"个数为3。718(即e+1,其中e为自然常数)。
Scaling effect of condensed matter physics and molecular physics
In 2005,"What is the nature of the glassy state?"was suggested as one of the greatest scientific conundrums over the next quarter century in an issue of Science on its 125th anniversary.In this study,the nature of the glassy state is investigated using the scaling law,where glass transition originates from the dynamic fluctuation(or cross-scale)between molecular physics(or molecular dynamics)and condensed matter physics,causing a discontinuous and nonequilibrium transition.(1)In physics,the glass transition is a classic order-to-disorder transition;in mathematics,it is an arrangement-to-combination transition;and in thermodynamics,it is a phase-to-microphase separation transition.(2)Cooperative dynamics(or molecule entanglement)in glass transition is confirmed using the Adam-Gibbs domain model,where there are 3.718 segments(e+1,where e is the natural constant).Moreover,approximately 78 molecules cooperatively move at the glass transition temperature.Therefore,research on glass transition becomes essential for exploring the working principles of the scaling effect in glassy matter and reconciling the interdisciplinary complexity of physics(condensed matter physics)and chemistry(molecular physics).

glassy matterglass transitionscaling effect

吕海宝、杜善义

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哈尔滨工业大学,特种环境复合材料技术国家级重点实验室,哈尔滨 150080

玻璃态物质 玻璃化转变 跨尺度力学

国家自然科学基金

11725208

2024

中国科学(物理学 力学 天文学)
中国科学院

中国科学(物理学 力学 天文学)

CSTPCD北大核心
影响因子:0.644
ISSN:1674-7275
年,卷(期):2024.54(5)