中国科学:技术科学(英文版)2024,Vol.67Issue(6) :1829-1841.DOI:10.1007/s11431-023-2640-2

Wettability regulation from superhydrophilic to superhydrophobic via nanosecond laser ablation

CHEN Zhi WU ZhiCheng ZHANG GuoJun LI DongHui HAN FengLin
中国科学:技术科学(英文版)2024,Vol.67Issue(6) :1829-1841.DOI:10.1007/s11431-023-2640-2

Wettability regulation from superhydrophilic to superhydrophobic via nanosecond laser ablation

CHEN Zhi 1WU ZhiCheng 2ZHANG GuoJun 3LI DongHui 4HAN FengLin2
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作者信息

  • 1. State Key Laboratory of Precision Manufacturing for Extreme Service Performance,College of Mechanical and Electrical Engineering,Central South University,Changsha 410083,China;Guangdong Provincial Key Laboratory of Manufacturing Equipment Digitization,Guangdong HUST Industrial Technology Research Institute,Dongguan 523808,China;China Harzone Industry Corp.,Ltd.,Wuhan 430299,China
  • 2. State Key Laboratory of Precision Manufacturing for Extreme Service Performance,College of Mechanical and Electrical Engineering,Central South University,Changsha 410083,China
  • 3. Guangdong Provincial Key Laboratory of Manufacturing Equipment Digitization,Guangdong HUST Industrial Technology Research Institute,Dongguan 523808,China
  • 4. China Harzone Industry Corp.,Ltd.,Wuhan 430299,China
  • 折叠

Abstract

Metal surfaces play a crucial role in numerous applications,from self-cleaning and anti-icing to anti-fogging and oil-water separation.The regulation of their wettability is essential to enhance their performance in these areas.This paper proposes a multi-state regulation method for metal surface wettability,leveraging nanosecond laser ablation.By creating non-uniform microstructures on a metal surface,the contact area between the solid and liquid phases can be increased,resulting in the attainment of superhydrophilic properties(contact angle(CA),ranging from 4.6° t0 8.5°).Conversely,the construction of uniform microstructures leads to a decreased solid-liquid contact area,thereby rendering the metal surface hydrophilic(CA=12.2°-53°).Furthermore,through heat treatment on a surface with uniform microstructures,organic matter adsorption can be promoted while simultaneously reducing surface energy.This process results in the metal surface acquiring hydrophobic properties(CA=92.1°-133.5°),facilitated by the"air cushion effect."Building on the hydrophobic surface,stearic acid modification can further reduce surface energy,ultimately bestowing the metal surface with superhydrophobic properties(CA=150.1°-152.7°,and sliding angle=3.8°).Performance testing has validated the durability and self-cleaning effectiveness of the fabricated superhydrophobic surface while also highlighting the excellent anti-fog performance of the superhydrophilic surface.These findings strongly indicate the immense potential of these surfaces in various engineering applications.

Key words

nanosecond laser ablation/surface wettability/superhydrophobic/superhydrophilic

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基金项目

Natural Science Foundation of Hunan Province,China(2023JJ30669)

Natural Science Foundation of Changsha City,China(kq2208273)

Fundamental Research Funds for the Central Universities of Central South University(2023ZZTS0967)

Fundamentals and Application Fundamentals Foundation of Guangdong Province,China(2022A15150I1226)

Project of State Key Laboratory of Precision Manufacturing for Extreme Service Performance,Central South University(ZZYJKT2022-10)

Project of Guangdong Provincial Key Laboratory of Manufacturing Equipment Digitization(2020B1212060014)

出版年

2024
中国科学:技术科学(英文版)
中国科学院

中国科学:技术科学(英文版)

CSTPCDEI
影响因子:1.056
ISSN:1674-7321
参考文献量1
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