Thermodynamic analysis of auto-thermal chemical looping hydrogen production systems

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外文摘要：Chemical looping hydrogen production is of interest because of its ability to simultaneously produce hydrogen and capture CO2 at the same time.Achieving an energy balance is crucial in chemical-looping hydrogen production systems.Decreasing the external heat duty can effectively reduce carbon capture and energy conversion efficiency.In this study,two auto-thermal chemical looping H2 generation systems are proposed.An adiabatic counter current moving bed chemical looping H2 generation system using CH4 as fuel and Fe2O3 and Al203(inert carriers)as oxygen carriers(OC)is proposed to analyse the energy balance and exergy balance of the systems.A parametric analysis was conducted to investigate the influence of the reaction ratio and temperature on the product outcomes,leading to the determination of optimal operating conditions.Subsequently,the impact of hydrogen production efficiency and reduction reactor outlet stream ratio and inert component proportion in the oxygen carrier on the system's thermal balance was analysed under these optimal conditions,culminating in the identification of key parameters for the two auto-thermal systems.Energy balance and exergy balance analyses were employed to compare the energy efficiency and irreversible losses of the autothermal and reference systems.The results demonstrated that the autothermal system enhanced the energy efficiency by 2.5％and the CO2 capture rate by 11％(percentage points)compared with the reference system.

外文关键词：

chemical looping hydrogen generationhydrogen productionauto-thermalenergy balance analysisexergy balance analysis

作者：

LI PeiJing、LIU TaiXiu、LI JiChao、QIN YuanLong、LIU QiBin

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作者单位：

School of Energy,Power,and Mechanical Engineering,North China Electric Power University,Beijing 102206,China

Institute of Engineering Thermophysics,Chinese Academy of Sciences,Beijing 100190,China

University of Chinese Academy of Sciences,Beijing 100049,China

Department of Thermal Science and Energy Engineering,University of Science and Technology of China,Hefei 230027,China

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出版年：

2024

DOI：

10.1007/s11431-024-2730-7

中国科学:技术科学(英文版)

中国科学院

中国科学:技术科学(英文版)

CSTPCDEI

影响因子：1.056

ISSN：1674-7321

年,卷(期)：2024.67(12)