具有超强二阶非线性响应及优良防潮性能的一种中性分子型DMPO有机新材料
A new neutral organic material DMPO with ultra-strong second-order nonlinear response and excellent anti-deliquescence
安然 1许向东 1李丙轩 2韩俊 1孙瑞良 1张敏刚 1蒋亚东1
作者信息
- 1. State Key Laboratory of Electronic Thin Films and Integrated Devices,School of Optoelectronic Science and Engineering,University of Electronic Science and Technology of China,Chengdu 611731,China
- 2. Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350102,China
- 折叠
摘要
具有强光学非线性和高稳定性的非线性光学(NLO)有机材料因其潜在的广泛应用而备受关注.本研究中,我们设计并系统地研究了具有超强二阶非线性光学响应的一种新型NLO查尔酮衍生物—1-(4-甲氧基苯基)-3-(4-乙氧基苯基)-2-丙烯基-1-酮(DMPO).合成得到的这种新设计的DMPO仅在5天内即可快速生长出尺寸为10 × 5 × 4mm3的DMPO单晶.这些DMPO晶体由中性有机分子组成,它们在较宽的波段600-1800 nm范围具有高透明性,还拥有适度的光学带隙(2.51 eV),并展现出卓越的抗潮解性能.重要的是,DMPO实测的二次谐波产生(SHG)响应高达基准材料4-(4-二甲氨基苯乙烯基)甲基吡啶对甲苯磺酸盐(DAST)的1.86倍,证实了DMPO具有优良的宏观二阶光学非线性性质.因此,DMPO是集多种优点于一身的一种有机NLO新材料,可广泛应用于NLO领域.
Abstract
Nonlinear optical(NLO)organic materials with large optical nonlinearity and high stability are highly at-tractive for wide applications.Herein,a new organic NLO chalcone derivative,1-(4-methoxy phenyl)-3-(4-ethoxy phe-nyl)-2-propenyl-1-ketone(DMPO),with an ultra-strong sec-ond-order nonlinear response was designed and systematically investigated.The as-designed DMPO was synthesized,and DMPO single crystals with a size of 10 × 5 × 4 mm3 were grown rapidly in only 5 days.The as-grown DMPO crystals formed by neutral organic molecules exhibit high transparency over a wide range of 600-1800 nm,a moderate optical band gap of 2.51 eV,and excellent anti-deliquescence.In particular,the second-harmonic generation response of DMPO reaches 1.86 times that of the benchmark material 4-N,N-dimethylamino-4'-N'-methyl-stilbazolium tosylate,revealing the outstanding macroscopic optical nonlinearity of DMPO,as designed.Therefore,DMPO combines several advantages,holding great potential for applications in nonlinear optics.
关键词
organic nonlinear material/DMPO/simulations/measurements/SHGKey words
organic nonlinear material/DMPO/simulations/measurements/SHG引用本文复制引用
基金项目
National Natural Science Foundation of China(61377063)
Sichuan Science and Technology Program(2022NSFSC0520)
出版年
2024
NETL
NSTL
万方数据