中国科学:材料科学(英文)2024,Vol.67Issue(12) :4040-4048.DOI:10.1007/s40843-024-3118-4

可实现超大拉伸应变的纳米尺寸硅机械超材料

Achieving ultra-large tensile strain in nanoscale Si mechanical metamaterials

黄语恒 尹奎波 高子健 李炳辉 聂萌 孙立涛
中国科学:材料科学(英文)2024,Vol.67Issue(12) :4040-4048.DOI:10.1007/s40843-024-3118-4

可实现超大拉伸应变的纳米尺寸硅机械超材料

Achieving ultra-large tensile strain in nanoscale Si mechanical metamaterials

黄语恒 1尹奎波 1高子健 1李炳辉 1聂萌 1孙立涛1
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作者信息

  • 1. SEU-FEI Nano-Pico Center,Key Laboratory of MEMS of Ministry of Education,Southeast University,Nanjing 210096,China
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摘要

不同于体硅材料在室温下的固有脆性特征,纳米尺寸硅材料因尺寸效应表现出更高的强度、塑性和滞弹性.然而,由于实验条件严苛,硅纳米结构的超大拉伸性能尚未得到证实.本研究通过对纳米尺寸硅样品进行转移、加工和测试等实验设计,在扫描电子显微镜中实现了纳米尺寸硅机械超材料原位拉伸测试,观察到高达95%超大拉伸应变.有限元仿真、原子级透射电子显微镜表征和分子动力学模拟表明,硅机械超材料的变形能力是聚焦离子束诱导尺寸软化和机械超材料几何结构力学改性共同作用的结果.本工作不仅有助于纳米材料、结构的强度、变形行为机理研究,也为硅纳米材料在纳机电系统和纳米应变工程中的潜在应用提供指导.

Abstract

Compared with the inherent brittleness of bulk silicon(Si)at ambient temperature,the nanosized Si materials with very high strength,plasticity,and anelasticity due to size effect,are all well-documented.However,the ultimate stretchability of Si nanostructure has not yet been demon-strated due to the difficulties in experimental design.Herein,directly performing in-situ tensile tests in a scanning electron microscope after developing a protocol for sample transfer,shaping and straining,we report the customized nanosized Si mechanical metamaterial which overcomes brittle limitations and achieves an ultra-large tensile strain of up to 95%using the maskless focused ion beam(FIB)technology.The un-precedented characteristic is achieved synergistically through FIB-induced size-softening effect and engineering modifica-tion of mechanical metamaterials,revealed through analyses of finite element analysis,atomic-scale transmission electron microscope characterization and molecular dynamics simula-tions.This work is not only instructive for tailoring the strength and deformation behavior of nanosized Si mechanical metamaterials or other bulk materials,but also of practical relevance to the application of Si nanomaterials in nanoelec-tromechanical system and nanoscale strain engineering.

关键词

Si/size effect/mechanical metamaterial/nano-structure/tensile strain

Key words

Si/size effect/mechanical metamaterial/nano-structure/tensile strain

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出版年

2024
中国科学:材料科学(英文)

中国科学:材料科学(英文)

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