矿业科学技术学报(英文版)2023,Vol.33Issue(6) :703-716.DOI:10.1016/j.ijmst.2023.01.002

Effect of hydrogen peroxide on selective flotation of chalcocite and enargite

Gde Pandhe Wisnu Suyantara Daniyarov Berdakh Hajime Miki Tsuyoshi Hirajima Keiko Sasaki Daishi Ochi Yuji Aoki
矿业科学技术学报(英文版)2023,Vol.33Issue(6) :703-716.DOI:10.1016/j.ijmst.2023.01.002

Effect of hydrogen peroxide on selective flotation of chalcocite and enargite

Gde Pandhe Wisnu Suyantara 1Daniyarov Berdakh 2Hajime Miki 3Tsuyoshi Hirajima 4Keiko Sasaki 1Daishi Ochi 5Yuji Aoki5
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作者信息

  • 1. Department of Earth Resources Engineering,Faculty of Engineering,Kyushu University,Fukuoka 819-0395,Japan;Kyushu University Institute for Asian and Oceanian Studies,Kyushu University,Fukuoka 819-0395,Japan
  • 2. Graduate School of Engineering,Faculty of Engineering,Kyushu University,Fukuoka 819-0395,Japan;Uzbekistan-Japan Innovation Center of Youth,Tashkent 100095,Uzbekistan
  • 3. Department of Earth Resources Engineering,Faculty of Engineering,Kyushu University,Fukuoka 819-0395,Japan
  • 4. Department of Earth Resources Engineering,Faculty of Engineering,Kyushu University,Fukuoka 819-0395,Japan;Sumitomo Metal Mining Co.,Ltd.,Tokyo 105-8716,Japan
  • 5. Sumitomo Metal Mining Co.,Ltd.,Ehime 792-0002,Japan
  • 折叠

Abstract

Enargite is typically associated with chalcocite.Owing to the similarity in the flotation behaviors of these minerals,both minerals are reported to concentrate in the conventional flotation circuit.However,inor-ganic arsenic in enargite can decrease the copper concentrate quality and increase the operating cost of processing this concentrate.Separating these minerals is important for cleaner copper production to avoid these effects.In this context,this study investigated the effect of hydrogen peroxide(H2O2)treat-ment on the flotation behavior of chalcocite and enargite.Flotation tests of pure and mixed minerals indi-cated that H2O2 treatment reduced the floatability of chalcocite and enargite by forming sulfate and copper hydroxide on their surfaces.Despite the detrimental effect of the H2O2 treatment,there was a nar-row window of H2O2 concentration for separating both minerals,in which enargite floated and chalcocite was depressed.This selective flotation behavior was caused by the rapid adsorption of potassium amyl xanthate(KAX)and lower surface oxidation of enargite compared with that of chalcocite.

Key words

Enargite/Chalcocite/Hydrogen peroxide/Potassium amyl xanthate/Selective flotation

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基金项目

Sumitomo Metal Mining Co.,Ltd.,Japan International Cooperation Agency(JICA)()

a Grantin-Aid for Science Research(JSPS KAKENHI)from the Japan Society for the Promotion of Science(JSPS)(JP22K14636)

a Grantin-Aid for Science Research(JSPS KAKENHI)from the Japan Society for the Promotion of Science(JSPS)(JP22H00310)

a Grantin-Aid for Science Research(JSPS KAKENHI)from the Japan Society for the Promotion of Science(JSPS)(JP19H02659)

Advanced Research Infrastructure for Materials and Nanotechnology(JPMXP1222KU1009)

Ministry of Education,Culture,Sports,Science and Technology(MEXT) Japan()

出版年

2023
矿业科学技术学报(英文版)
中国矿业大学

矿业科学技术学报(英文版)

CSTPCDCSCD北大核心EI
影响因子:1.222
ISSN:2095-2686
参考文献量3
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