矿业科学技术学报(英文版)2024,Vol.34Issue(3) :305-321.DOI:10.1016/j.ijmst.2024.02.003

A novel nano-grade organosilicon polymer:Improving airtightness of compressed air energy storage in hard rock formations

Zhuyan Zheng Guibin Wang Chunhe Yang Hongling Ma Liming Yin Youqiang Liao Kai Zhao Zhen Zeng Hang Li Yue Han
矿业科学技术学报(英文版)2024,Vol.34Issue(3) :305-321.DOI:10.1016/j.ijmst.2024.02.003

A novel nano-grade organosilicon polymer:Improving airtightness of compressed air energy storage in hard rock formations

Zhuyan Zheng 1Guibin Wang 1Chunhe Yang 1Hongling Ma 1Liming Yin 2Youqiang Liao 1Kai Zhao 1Zhen Zeng 1Hang Li 2Yue Han3
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作者信息

  • 1. Institute of Rock and Soil Mechanics,Chinese Academy of Sciences,Wuhan 430071,China;University of Chinese Academy of Sciences,Beijing 100049,China;State Key Laboratory of Geomechanics and Geotechnical Engineering,Wuhan 430071,China
  • 2. State Key Laboratory of Coal Mine Disaster Dynamics and Control,Chongqing University,Chongqing 400044,China
  • 3. PowerChina Huadong Engineering Corporation Limited,Hangzhou 310014,China
  • 折叠

Abstract

Enhancing cavern sealing is crucial for improving the efficiency of compressed air energy storage(CAES)in hard rock formations.This study introduced a novel approach using a nano-grade organosilicon poly-mer(NOSP)as a sealant,coupled with an air seepage evaluation model that incorporates Knudsen diffu-sion.Moreover,the initial coating application methods were outlined,and the advantages of using NOSP compared to other sealing materials,particularly regarding cost and construction techniques,were also examined and discussed.Experimental results indicated a significant reduction in permeability of rock specimens coated with a 7-10 μm thick NOSP layer.Specifically,under a 0.5 MPa pulse pressure,the permeability decreased to less than 1 nD,and under a 4 MPa pulse pressure,it ranged between 4.5×10-6-5.5×10-6 mD,marking a 75%-80%decrease in granite permeability.The sealing efficacy of NOSP surpasses concrete and is comparable to rubber materials.The optimal viscosity for application lies between 95 and 105 KU,and the coating thickness should ideally range from 7 to 10 μm,applied to sub-strates with less than 3%porosity.This study provides new insights into air transport and sealing mech-anisms at the pore level,proposing NOSP as a cost-effective and simplified solution for CAES applications.

Key words

Compressed air energy storage/Lining/Permeability/Transient pulse method/Hard rock cavern/Nano-grade organosilicon polymer coating

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基金项目

国家自然科学基金(42272321)

Hubei Provincial Key Research Projects(2022BAA093)

Hubei Provincial Key Research Projects(2022BAD163)

Major Scientific and Technological Special Project of Jiangxi Province(2023ACG01004)

WSGRI Engineering & Surveying Incorporation Limited(6120230256)

出版年

2024
矿业科学技术学报(英文版)
中国矿业大学

矿业科学技术学报(英文版)

CSTPCDCSCDEI
影响因子:1.222
ISSN:2095-2686
参考文献量6
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