首页|Elucidating the enhancement of kaolinite flotation by iron content through density functional theory:A study on sodium oleate adsorption efficiency

Elucidating the enhancement of kaolinite flotation by iron content through density functional theory:A study on sodium oleate adsorption efficiency

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This study delves into the intricate relationship between iron(Fe)content in kaolinite and its impact on the adsorption behavior of sodium oleate.The effects of different iron concentrations on adsorption energy,hydrogen bond kinetics and adsorption efficiency were studied through simulation and experi-mental verification.The results show that the presence of iron in the kaolinite structure significantly improves the adsorption capacity of sodium oleate.Kaolinite samples with high iron content have better adsorption properties,lower adsorption energy levels and shorter and stronger hydrogen bonds than pure kaolinite.The optimal concentration of oleic acid ions for achieving maximum adsorption efficiency was identified as 1.2 mmol/L across different kaolinite samples.At this concentration,the adsorption rates and capacities reach their peak,with Fe-enriched kaolinite samples exhibiting notably higher flota-tion recovery rates.This optimal concentration represents a balance between sufficient oleic acid ion availability for surface interactions and the prevention of self-aggregation phenomena that could hinder adsorption.This study offers promising avenues for optimizing the flotation process in mineral process-ing applications.

Iron InfluenceSodium Oleate AdsorptionKaolinite SurfacesMolecular Interaction AnalysisFlotation Efficiency Optimization

Lingyun Liu、Chuilei Kong、Hongyu Zhao、Fangqin Lu

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Joint National-Local Engineering Research Centre for Safe and Precise Coal Mining,Huainan 232001,China

Department of Materials Science and Engineering,Anhui University of Science and Technology,Huainan 232001,China

School of Civil and Resource Engineering,University of Science and Technology Beijing,Beijing 100083,China

Natural Science Foundation of ChinaOpen Research Grant of Joint National-Local Engineering Research Centre for Safe and Precise Coal MiningOpen Research Grant of Joint National-Local Engineering Research Centre for Safe and Precise Coal MiningAnhui University of Science and Technology 2023 Graduate Student Innovation FundOpen Research Grant of Anhui Engineering Research Center for Coal Clean Processing and Carbon Emission Reduction

No.52174232Nos.EC2022003EC2023005No.2023cx2106No.CCCE-2023003

2024

10.1016/j.ijmst.2024.06.007

矿业科学技术学报(英文版)
中国矿业大学

矿业科学技术学报(英文版)

CSTPCDEI
影响因子：1.222
ISSN：2095-2686
年,卷(期)：2024.34(6)
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