首页|基于颗粒堆积法的煤体表面弛豫率量化初探

基于颗粒堆积法的煤体表面弛豫率量化初探

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为了确定煤岩表面弛豫率ρ值来量化其弛豫特性与孔径分布的对应关系,聚焦井下海量打钻工序所产生的煤屑颗粒,提出了基于颗粒堆积法的煤体ρ值计算方法,构建了球形煤屑基质-球形总孔隙结构的计算模型,选择平煤股份二矿己15和己17煤层煤样进行模型验证.结果表明:不同粒径煤屑堆积样品的弛豫谱图呈近似的三峰形态,同一煤样不同粒径饱水煤屑堆积体可表现出不同的弛豫响应行为,弛豫时间T2的几何平均值T2m和核磁孔隙率φNMR值分布的差异性主要受水赋存特征、煤屑润湿性及堆积方式等多种因素的影响.通过线性拟合横向弛豫总弛豫率T2-1和有效孔隙指标与煤粒有效长度之比φg/wgrain及其95%置信区间分布,证实了直接采用恒定ρ值计算煤岩孔隙结构的不合理性.不同形状煤屑基质-总孔隙结构的计算模型获得的ρ值范围不同,表明不同形状煤屑间的流体扩散路径和接触特征不同,易引起煤屑堆积体的弛豫行为不同.未考虑煤屑间的体积流体效应而忽略T2b影响,易造成ρ值偏大.
Preliminary study on quantitative calculation of coal surface relaxivity based on particle packing method
The determination of the surface relaxivity ρ for coal and rock was used to quantita-tively characterize the relationship between their relaxation properties and pore size distribu-tion,focusing on large amount of coal particles produced during the drilling process,a method of coal ρ value calculation was proposed based on coal particle packing.A calculation model of the spherical coal detritor-spherical total pore structure was constructed.The coal samples from Ji 15 and Ji 17 coal seams in No.2 Mine,Pingdingshan Tianan Coal Industry Co.,Ltd.,were selected for model verification.The results show that the relaxation spectra of coal parti-cles with different particle sizes exhibit a similar three-peak shape,and the same water-saturat-ed coal particle deposits with different particle sizes can exhibit different relaxation response behaviors.The differences of T2m and φNMR values are mainly affected by water occurrence char-acteristics,coal debris wettability and packing mode.By linear fitting of T2-1 and φg/wgrain and 95%confidence interval distribution,it is proved that it is unreasonable to calculate the pore structure of coal rock directly with constant ρ value.The range of ρ values obtained by the cal-culation model of the matrix-total pore structure for coal cuttings with different shapes is dif-ferent,which indicates that the fluid diffusion path and contact characteristics between coal cuttings with different shapes are different,and it is easy to be different for the relaxation be-havior of coal cuttings deposits.Ignoring the T2b effect without considering the volume fluid effect among coal cuttings,the ρ value is likely to be too large.

low field nuclear magnetic resonancepore structuresurface relaxivityparticle packingnuclear magnetic porosity

徐吉钊、徐鹤翔、翟成、丁熊、桑树勋、李全贵、孙勇、余旭、丛钰洲、郑仰峰、唐伟、牛积战、耿进军

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中国矿业大学煤矿瓦斯与火灾防治教育部重点实验室 江苏徐州 221116

中国矿业大学安全工程学院 江苏徐州 221116

中国矿业大学碳中和研究院 江苏徐州 221116

重庆大学煤矿灾害动力学与控制国家重点实验室 重庆 400044

中国矿业大学低碳能源与动力工程学院 江苏徐州 221116

中国平煤神马能源化工集团有限责任公司平煤股份二矿 河南平顶山 467000

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低场核磁共振 孔隙结构 表面弛豫率 颗粒堆积 核磁孔隙率

国家自然科学青年基金项目国家杰出青年科学基金项目中国博士后科学基金项目中央高校基本科研业务费专项资金项目

52104228519254042021M6934092023ZDPY05

2024

中国矿业大学学报
中国矿业大学

中国矿业大学学报

CSTPCD北大核心
影响因子:1.83
ISSN:1000-1964
年,卷(期):2024.53(1)
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