首页|白钨矿捕收剂的温度响应机制研究

白钨矿捕收剂的温度响应机制研究

Study on the temperature response mechanism of scheelite collector

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为探究不同白钨矿捕收剂对环境温度的响应差异和机制.采用单矿物浮选试验,系统研究了油酸钠和3种羟肟酸浮选白钨矿的温度响应规律,并通过接触角试验、表面张力测量、流变学研究、浊度试验、Zeta电位测试以及吸附量试验,揭示了温度对捕收剂性能影响的内在机制.结果表明:随着浮选温度的降低,所有捕收剂的捕收能力均有所减弱,其中油酸钠受温度影响更为显著.温度降低导致捕收剂表面张力增加、矿浆黏度增大、药剂溶解性变差.这些因素共同作用,使得捕收剂分子与矿粒的碰撞概率下降,药剂在矿粒表面的吸附量减少,最终导致作用于白钨矿颗粒表面的药剂分子数量减少,降低了矿粒表面的疏水性,严重恶化了浮选效果.
To investigate the differences and mechanisms of the response of different scheelite collectors to temperature.The temperature response law of sodium oleate and three kinds of hydroxamic acid flotation of scheelite was systematically investigated by using single-mineral flotation tests,and the intrinsic mechanism of the influence of temperature on the performance of the collectors was revealed by the contact angle tests,surface tension measurements,rheo-logical study,turbidity tests,Zeta potential tests,and adsorption tests.The results show that with the decrease of flotation temperature,the capture capacity of all the collectors is signifi-cantly weakened,among which sodium oleate is more significantly affected by temperature.The decrease in temperature leads to an increase in the surface tension of the collector,an in-crease in the viscosity of the slurry,and a deterioration in the solubility of the reagent.The combined effect of the above factors makes the collision probability between the collector mole-cules and the ore particles decrease,and the adsorption amount of the reagent on the surface of the ore particles decreases,which ultimately leads to a decrease in the number of reagent mole-cules acting on the surface of scheelite particles,reduces the hydrophobicity of the surface of the ore particles,and seriously deteriorates the flotation effect.

low temperature flotationscheelitehydroxamic acidpowder contact angle

卜显忠、王亮、薛季玮、张崇辉、王森、宛鹤

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西安建筑科技大学资源工程学院,陕西西安 710055

低温浮选 白钨矿 羟肟酸 粉末接触角

国家自然科学基金项目陕西省重点研发计划国际合作项目-重点项目

520742062021KWZ-16

2024

中国矿业大学学报
中国矿业大学

中国矿业大学学报

CSTPCD北大核心
影响因子:1.83
ISSN:1000-1964
年,卷(期):2024.53(2)
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