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纤维聚合物柔韧混凝土微观孔隙结构特征与增强机理

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针对传统混凝土在井下实际应用时表现出强度低、脆性大、韧性差等缺陷性问题,提出通过加入聚合物和纤维形成复合材料的方式进行改善.通过电子计算机断层扫描技术(CT)、扫描电子显微镜(SEM)研究复合材料的强度、韧性、孔隙结构和纤维分布.结果表明:在混凝土中加入玄武岩纤维(BF)和乙烯-醋酸乙烯酯共聚乳液(VAE聚合物)后,BF通过填充孔隙,使得混凝土中原始孔隙尺寸与数量降低,VAE聚合物通过一系列水化反应得到聚合物薄膜,附着在BF与基体骨料表面,从而增加黏结性能,达到增强增韧的效果;单一尺寸BF掺入条件下,BF掺量为3.0 kg/m3、VAE聚合物掺量为3%左右、BF长度为9 mm左右时,混凝土力学性能提升效果最好;在前期试验的基础上通过调整3种尺寸BF在混凝土中的掺入比例,设计多尺寸BF混掺,与前期试验相比,整体力学性能得到提升;利用数字图像处理技术对切片进行灰度值调节,将密度相同的基体与纤维准确区分,得到清晰的内部结构灰度图,从而实现纤维可视化;借助CT扫描结果和SEM图像进行细观结构研究,结果显示,同一 BF尺寸下,混凝土内部孔隙数量随着BF掺量的增加先减少后增加,相比之下多尺寸BF混掺下试样孔隙率偏小、孔隙数量少.研究结果可为软岩巷道大变形支护研究和混凝土复合材料的细观孔隙结构演化提供借鉴.
Microscopic pore structure characteristics and strengthening mechanism of fiber polymer flexible concrete
In view of the defective problems such as low strength,brittleness,and poor tough-ness exhibited by traditional concrete in down hole practical applications,the mechanical prop-erties of concrete can be improved by adding polymers and fibers to form composite materials.The mechanical strength,toughness,pore structure and fiber distribution of the composites were studied by Computed Tomography(CT)and Scanning Electron Microscope(SEM).It has been shown that when basalt fibers(BF)and vinyl acetate-ethylene copolymer(VAE poly-mers)are added to concrete,BF reduces the size and number of original pores in concrete by filling pores.VAE polymer obtains a polymer film through a series of hydration reactions,which is attached to the surface of BF and matrix aggregate,thereby increasing the bonding performance and achieving the effect of strengthening and toughening.Under single-size BF ad-mixture conditions,the best effect on concrete mechanical property enhancement was observed at fiber admixture of 3.0 kg/m3,VAE polymer dosage of about 3%and BF length of about 9 mm.On the basis of the preliminary test by adjusting the mixing ratio of three sizes of BF in concrete,the design of multi-size BF mixing,compared with the preliminary test,the overall mechanical properties of the foundation test has been improved.Using digital image processing technology to adjust the gray value of the slices,the matrix with the same density is accurately differentiated from the fibers,and a clear grayscale map of the internal structure is obtained,thus realizing the visualization of the fibers.The fine structure study with the help of CT scan-ning results and SEM images shows that the number of pores inside the concrete decreases and then increases with the increase of BF admixture for the same BF size,compared to the small porosity and less number of BF in the specimen under the multi-size BF mix.The results of the study can be useful for the study of large deformation support of soft rock tunnel and the evo-lution of fine-scale pore structure of concrete composites.

basalt fibreVAE polymerCT scanningSEMpore

马建宏、王琪、焦华喆、杨柳华、王春来、张勃阳、陈曦

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河南理工大学土木工程学院,河南焦作 454003

河南理工大学能源科学与工程学院,河南焦作 454003

煤炭安全生产与清洁高效利用省部共建协同创新中心,河南焦作 454000

中国矿业大学(北京)能源与矿业工程学院,北京 100083

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BF纤维 VAE聚合物 CT扫描 SEM 孔隙

2024

中国矿业大学学报
中国矿业大学

中国矿业大学学报

CSTPCD北大核心
影响因子:1.83
ISSN:1000-1964
年,卷(期):2024.53(6)