首页|气相色谱仪测定工业氢中微量杂质气

气相色谱仪测定工业氢中微量杂质气

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对现有的Trace 1310 气相色谱仪进行改造,加装镍转化炉、氢火焰离子化检测器(FID),以及分子筛柱替换脱氧柱,建立了一点校正法,一次进样不受前后进样温度和压力的影响,完成工业氢中O2+Ar、N2、CO、CO2、CH4 的检测,其相对标准偏差为 3.21%~4.92%、加标回收率为 97.60%~100.79%,操作简便、分析速度快,为公司回用高盐废水深度治理装置制氢或者新购工业氢提供了品质判定依据.
Trace 1310 gas chromatograph was used to determine trace impurity gases in industrial hydrogen
The existing Trace 1310 gas chromatograph was remoulded by adding a nickel reformer,flame ionization detector(FID)and a molecular sieve column to replace the deoxidization column,in order to set up one point correction method.The point correction method is used to analyze trace impurity gases such as O2+Ar,N2,CO,CO2 and CH4 in industrial hydrogen,having the advantage of a sample injection which is not affected by the temperature and pressure before and after the injection.The relative standard deviation and recovery rate were 3.21%~4.92%and 97.60%~100.79%seperatively by this simple method.It provides the basis for the quality judgment of hydrogen production or newly purchased industrial hydrogen in the high-salt wastewater advanced treatment unit of our company,which the operation is simple and the analysis speed is fast.

national standardsgas chromatographthermal conductivity detectorflame ionization detectorone point correction method

胡芳、刘清海、于荣强、李珍、胡华斌、许冲

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河南佰利联新材料有限公司,河南 焦作

龙佰集团股份有限公司,河南 焦作

焦作煤业(集团)有限责任公司,河南 焦作

国家标准 气相色谱法 热导检测器 氢火焰离子化检测器 一点校正法

2024

中国氯碱
中国氯碱工业协会

中国氯碱

影响因子:0.164
ISSN:1009-1785
年,卷(期):2024.(1)
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