首页|堆存锰渣中重金属污染物性质及固化研究

堆存锰渣中重金属污染物性质及固化研究

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为了解决锰渣的无害化处理,对某堆存锰渣进行了全量、形态和固化分析.结果表明:堆存锰渣中含有大量重金属污染物,且大部分污染物的可溶性形态占比较高,其中全Mn含量超过相关标准限值,浸出液中Mn2+、Ni2+浓度超过排放限值.选用石灰石作为固化剂对堆存锰渣进行固化后,浸出液中Mn2+、Ni2+的含量显著下降,当其加入质量分数为2%时,浸出液中Ni2+的浓度达到排放标准要求,增至6%后Mn2+浓度达标;固化后堆存锰渣中污染物的可溶性形态占比明显降低,残渣态占比升高,污染物活性显著下降,表明石灰石对堆存锰渣无害化处理有较好的效果.
Study on the Properties and Solidification of Heavy Metal Pollutants in Stockpiling Manganese Slag
In order to solve the problem of harmless treatment of manganese slag,a component,morphological,and solidification analysis was conducted on the stockpiling manganese slag.The results show that the stockpiling manganese slag contains a large amount of heavy metal pollutants,and most of the pollutants have a high proportion of soluble forms.The total Mn content exceeds the relevant standard limits,and the concentrations of Mn2+and Ni2+in the leachate exceed the emission limits;Using limestone as a solidifying agent to solidify stockpiling manganese slag,the content of Mn2+and Ni2+in the leachate significantly decreased.When a mass fraction of 2%was added,the concentration of Ni2+in the leachate met the emission standard requirements.After increasing to 6%,the concentration of Mn2+met the standard;After solidification,the proportion of soluble forms of pollutants in the stockpiling manganese slag significantly decreases,the proportion of insoluble forms increases,and the activity of pollutants significantly decreases,indicating that limestone has a good effect on the harmless treatment of stockpiling manganese slag.

Electrolytic manganese slagHeavy metal pollutantsToxicity leachingForm DistributionSolidification

曾胜、杨艳、蒲冬林、程燕琳、曹小林

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四川省第十地质大队,四川 绵阳 621000

电解锰渣 重金属污染物 毒性浸出 形态分布 固化

2024

中国锰业
全国锰业技术委员会 湖南特种金属材料厂

中国锰业

CSTPCD
影响因子:0.432
ISSN:1002-4336
年,卷(期):2024.42(3)
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