首页|二氧化锰对生活饮用水中氟化物的去除性能研究

二氧化锰对生活饮用水中氟化物的去除性能研究

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通过水热法合成了4 种不同晶型的MnO2 吸附剂,并分别对其除氟能力进行了研究和比较.评估了处理时间、吸附剂用量、初始氟化物浓度、溶液初始pH、共存离子等因素对吸附剂吸附性能的影响.结果表明,4 种吸附剂中δ-MnO2 对氟离子的去除效果最佳.当吸附剂用量为6g/L,初始氟离子浓度为10 mg/L,pH为5 时,10 h内达到吸附平衡,去除率高达95.9%.此外,还在自然条件下使用生活饮用水样品进行了吸附实验,氟化物含量从5mg/L降低至0.715 mg/L,低于世界卫生组织最大允许限值.
A Study on the Removal Performance of Manganese Dioxide in Fluoride Removal From Drinking Water
Four different crystal forms of MnO2 adsorbents were synthesized by the hydrothermal method,and their fluoride removal abilities were studied and compared.The effects of processing time,adsorbent dosage,initial fluoride concentration,initial solution pH,and coexisting ions on the adsorption performance were evaluated.Among the four adsorbents,δ-MnO2 exhibited the highest fluoride removal efficiency.Adsorption equilibrium was achieved within 10 hours at an adsorbent dosage of 6 g/L,an initial fluoride ion concentration of 10 mg/L,and a pH of 5,with a removal rate of 95.9%.Furthermore,adsorption experiments performed using drinking water samples under natural conditions resulted in a fluoride content decrease from 5 mg/L to 0.715 mg/L,which is below the World Health Organization's maximum allowable limit.

Manganese dioxideAdsorbentDrinking waterFluoride removal

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上海市政工程设计研究总院(集团)有限公司,上海 200092

二氧化锰 吸附剂 生活饮用水 除氟

2024

中国锰业
全国锰业技术委员会 湖南特种金属材料厂

中国锰业

CSTPCD
影响因子:0.432
ISSN:1002-4336
年,卷(期):2024.42(3)