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磷酸锰铁锂正极材料的制备与改性策略

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磷酸锰铁锂(LMFP)是一种具有高能量密度、高稳定性、高安全性和长循环寿命等优势的锂离子电池正极材料.磷酸锰铁锂在下游行业中的需求量逐年增大,进而促进了对其规模化制备的工艺路线优化与探索.锰元素的引入虽改进了原有锂离子电池正极材料的部分性能,但也引发了电导率低、锰溶出等新问题的产生,因此需要在成熟工业生产基础上对磷酸锰铁锂进行改性,优化电池性能,推动产业更进一步发展.在此背景下,通过详细综述目前常用的磷酸锰铁锂制备方式和改性策略,分析了各种方式工业化生产的可行性,讨论了改性磷酸锰铁锂的性能优势,并为其未来研究和产业化发展方向提出了见解与期望.
Preparation and Modification Strategy of Lithium Manganese Iron Phosphate Cathode Materials
Lithium Manganese iron phosphate(LMFP)is a positive electrode material for lithium-ion batteries with advantages such as high energy density,high stability,high safety,and longer cycle life.The increasing demand for LMFP in downstream industries has promoted the optimization and exploration of process routes for its large-scale preparation.The introduction of manganese has improved some of the performance of the original lithium-ion battery cathode materials,but it has also caused new problems such as low conductivity and manganese leaching.Therefore,it is necessary to modify LMFP and further improve its properties through modification to optimize battery performance and promote further development of the industry.In this context,a detailed review of the commonly used preparation methods and modification strategies for LMFP is provided,and the feasibility of various industrial production methods is analyzed.The performance advantages of modified LMFP are discussed,and insights and expectations are offered for its future research and industrial development direction.

Lithium Manganese iron phosphateLithium-ion batteryCathode materialsPreparation strategiesPerformance optimization

唐杰峰、王子俊、陈奇志、吴博宁、聂艳媚、秦影、喻林萍

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长沙理工大学化学化工学院,湖南 长沙 410114

广西汇元锰业有限责任公司,广西 来宾 546138

磷酸锰铁锂 锂离子电池 正极材料 制备策略 性能优化

广西来宾市科技局科技计划项目广西来宾市科技局科技计划项目

20230030270240101

2024

中国锰业
全国锰业技术委员会 湖南特种金属材料厂

中国锰业

CSTPCD
影响因子:0.432
ISSN:1002-4336
年,卷(期):2024.42(4)