锰基锂离子电池正极材料研究进展综述
Review of Research Progress on Positive Electrode Materials for Manganese-Based Lithium-ion Batteries
吴才可 1韦泽羽 1李良 2金晶 2詹海青 3张丽云 3司徒白雪 2杨勇 3江卫良 4李致朋 5韦庆锰 6李玉婷 6莫燕娇 6甘永兰 6杨雄强 6詹锋 1陈发明3
作者信息
- 1. 广西大学资源环境与材料学院,广西 南宁 530004
- 2. 深圳中芯能科技有限公司,广东 深圳 518000
- 3. 南方锰业集团有限责任公司,广西 南宁 530200
- 4. 深圳永泰数能科技有限公司,广东 深圳 518000
- 5. 深圳市致远动力科技有限公司,广东 深圳 518055
- 6. 广西锰华新能源科技发展有限公司,广西 钦州 535000
- 折叠
摘要
通过对富锂锰基电池、锰酸锂电池、镍钴锰酸锂电池、磷酸锰铁锂电池对应的4 种锰基正极材料进行综述,分别分析了富锂锰基、锰酸锂、镍钴锰、磷酸锰铁锂4 种正极材料的研究进展,并介绍了掺杂、包覆、煅烧温度调节、氧气空位调节等提高材料性能的方法.为锰基锂离子电池正极材料的发展提供了分析,尤其是在提高能量密度、循环稳定性和安全性方面的改性策略.希望通过对材料不断地创新和优化,为锰基锂离子电池在新能源领域的应用发挥更大作用提供相关参考.
Abstract
This article reviews four types of manganese-based cathode materials corresponding to lithium-rich manganese-based batteries,lithium manganese oxide batteries,nickel-cobalt-manganese oxide batteries,and lithium manganese iron phosphate batteries.The advantages and disadvantages of these four cathode materials are analyzed,and methods for improving material performance,including doping,coating,calcination temperature adjustment,and oxygen vacancy adjustment,are introduced.This provides an analysis for the development of positive electrode materials for manganese-based lithium-ion batteries,especially in terms of modification strategies to improve energy density,cycle stability,and safety.It is hoped to provide relevant references for the application of manganese-based lithium-ion batteries in the field of new energy through continuous innovation and optimization of materials.
关键词
锰基锂离子电池/正极材料/能量密度/循环稳定性Key words
Manganese-based lithium-ion battery/Positive electrode material/Energy density/Cyclic stability引用本文复制引用
基金项目
国家自然科学基金(11364003)
广西创新驱动重大专项桂科(AA19182014)
出版年
2024