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香蕉中啶氧菌酯残留行为和膳食风险评估

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香蕉生产中普遍使用啶氧菌酯,这可能对消费者健康造成潜在风险.为了评估膳食风险,我们拟研究香蕉中啶氧菌酯残留行为,在海南和云南两地分别开展香蕉中啶氧菌酯消解动态和最终残留试验,于施药后不同时间采样检测样品中啶氧菌酯残留,并计算膳食风险商.结果表明,在添加浓度0.02~1.0 mg/kg范围内,香蕉中啶氧菌酯的平均回收率为101.4%~109.2%,相对标准偏差为2.1%~4.0%,最小检出量为0.01 ng,最低检出浓度为0.02 mg/kg.香蕉中啶氧菌酯降解符合一级动力学方程,降解半衰期为8.7~13.8 d,最终残留量的最大值为0.045 mg/kg,施药60 d后香蕉中啶氧菌酯降解率大于99.62%.我国普通成人啶氧菌酯的估算每日摄入量估计为0.35 mg,风险商(RQ)为0.06,远远小于1.说明在该试验条件下,香蕉中啶氧菌酯的残留水平不会对普通成人造成膳食风险.
Residue behavior and dietary risk assessment of picoxystrobin in banana
Picoxystrobin is commonly used in banana production,which is a potential risk to consumer's health.To evaluate the dietary risk of picoxystrobin,residue behavior of picoxystrobin in banana was studied through experiment on the dissipation dynamics and residue of picoxystrobin in banana in Hainan and Yunnan Provinces.Residues of picoxystrobin in bananas harvested at different time after application of picoxystrobin was tested,and the dietary risk quotient(RQ)was calculated.The results showed that in the range of 0.02-1.0 mg/kg,the average recoveries of picoxystrobin in banana was 101.4%-109.2%,with the RSD of 2.1%-4.0%,the minimum detectable amount of 0.01 μg and the minimum detected concentration of 0.02 mg/kg.The degradation of picoxystrobin in banana conformed to the first-order degradation kinetic equation,with the half-life of 7.7-13.9 d.The maximal final residue was 0.045 mg/kg.The degradation rate of picoxystrobin in banana was more than 99.62%after 60 days of application.The NEDI of picoxystrobin for ordinary adult in China is 0.35 mg,and the RQ is 0.06,which is far less than 1.The residual levels of picoxystrobin in bananas did not pose a dietary risk to general adults.

banana(Musa acuminata)picoxystrobinresidedietary riskrecovery

田海、冯玉洁、罗激光、吉训聪、徐志、王明月、马晨

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中国热带农业科学院分析测试中心/海南省热带果蔬产品质量安全重点实验室/农业农村部热作产品质量安全风险评估实验室,海口,571101

海南省农业科学院植物保护研究所/海南省农业科学院农产品质量安全与标准研究中心,海口,571100

香蕉 啶氧菌酯 残留 膳食风险 回收率

海南省自然科学基金海南省热带果蔬产品质量安全重点实验室项目

322MS107KFKT2022002

2024

中国南方果树
中国农业科学院柑桔研究所

中国南方果树

CSTPCD北大核心
影响因子:0.527
ISSN:1007-1431
年,卷(期):2024.53(2)
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