首页|Regulation of Pore Structure and High-temperature Fracture Behavior of CAC-bonded Alumina-Spinel Castables Based on Hydration Design
Regulation of Pore Structure and High-temperature Fracture Behavior of CAC-bonded Alumina-Spinel Castables Based on Hydration Design
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The lamellar hydrates of CAC were designed with the introduction of nano CaCO3 or Mg-Al hydrotalcite(M-A-H),and the effects on the green strength,pore structures,and high-temperature fracture behavior of alumina-spinel castables were investigated.The results show that nano CaCO3 or M-A-H stimulates rapidly the hydration of CAC and the formation of lamellar C4AcH11 or coexistence of C2AH8 and C4AcH11 at 25 ℃.The formation of lamellar hydrates can contribute to a more complicated pore structure,especially in the range of 400-2 000 nm.Meanwhile,the incorporation of well-distributed CaO or MgO sources from nano CaCO3 or M-A-H also regulates the distribution of CA6 and spinel(pre-formed and in-situ).Consequently,the optimized microstructure and complicated pore structure can induce the deflection and bridging of cracks,thus facilitating the consumption of fracture energy and enhancing the resistance to thermal stress damage.
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