中国酿造2024,Vol.43Issue(12) :161-166.DOI:10.11882/j.issn.0254-5071.2024.12.024

基于HS-SPME-GC-MS技术对不同产地9种黄酒挥发性香气成分差异分析

Difference of volatile aroma components of 9 kinds of Huangjiu from different producing areas by HS-SPME-GC-MS

王进 陈涛 王新杰 骆业巧 于单
中国酿造2024,Vol.43Issue(12) :161-166.DOI:10.11882/j.issn.0254-5071.2024.12.024

基于HS-SPME-GC-MS技术对不同产地9种黄酒挥发性香气成分差异分析

Difference of volatile aroma components of 9 kinds of Huangjiu from different producing areas by HS-SPME-GC-MS

王进 1陈涛 1王新杰 2骆业巧 1于单2
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作者信息

  • 1. 宿迁市产品质量监督检验所,江苏宿迁 223800
  • 2. 嘉兴大学生物与化学工程学院,浙江嘉兴 314100
  • 折叠

摘要

为探究不同产地黄酒的品质差异,采用顶空固相微萃取-气相色谱-质谱(HS-SPME-GC-MS)技术,对不同产地9种黄酒样品的挥发性香气成分进行分析.结果表明,不同产地黄酒中共检测出香气成分109种,其中醇类、酯类和醛类物质是构成黄酒香气的基础.基于香气成分正交偏最小二乘法判别分析(OPLS-DA)和聚类分析可以有效区分不同产地的黄酒,其中7种差异香气成分可用于黄酒的产地鉴别.结合香气活力值(OAV)及变量投影重要性(VIP)值分析,共筛选出24种关键香气化合物(OAV>1)及7种差异香气化合物(OAV>1,VIP>1),其中乙酸异戊酯、苯甲酸乙酯、丁酸乙酯、己酸乙酯、2,4-二叔丁基苯酚、苯乙醇、苯甲醛对黄酒整体香气贡献较大.

Abstract

In order to investigate the quality difference of Huangjiu from different producing areas,the volatile aroma components of 9 kinds of Huangjiu samples from different producing areas were analyzed by headspace solid phase microextraction gas chromatography-mass spectrometry(HS-SPME-GC-MS).The results showed that 109 kinds of aroma components were detected in Huangjiu from different producing areas,among which alcohols,esters and aldehydes were the basis of aroma.Based on the orthogonal partial least squares discriminant analysis(OPLS-DA)and cluster analysis,Huangjiu from different producing areas could be distinguished effectively,among which 7 kinds of difference aroma components could be used for producing areas identification of Huangjiu.Combined with the analysis of aroma activity value(OAV)and variable projection importance(VIP)value,24 key aroma compounds(OAV>1)and 7 different aroma compounds(OAV>1,VIP>1)were screened,among which isoamyl acetate,ethyl ben-zoate,ethyl butyrate,ethyl caproate,2,4-di-tert-butylphenol,phenylethanol and benzaldehyde contributed to the overall aroma of Huangjiu.

关键词

黄酒/香气差异/香气活力值/顶空固相微萃取-气质联用

Key words

Huangjiu/aroma difference/odor activity value/headspace solid-phase microextraction-gas chromatography-mass spectrometry

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出版年

2024
中国酿造
中国调味品协会 北京食品科学研究院

中国酿造

CSTPCD北大核心
影响因子:0.759
ISSN:0254-5071
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