首页|The Formation of SO2 and Emission Reduction Solutions in the Preparation of a Hydrogenation Catalyst Support
The Formation of SO2 and Emission Reduction Solutions in the Preparation of a Hydrogenation Catalyst Support
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The key reason for SO2 formation during the production of a residue hydrogenation catalyst support was identified and subsequent emission reduction solutions were then investigated and verified systematically.The results demonstrated that carbon-containing organic materials,including sesbania powder and cellulose,did not completely decompose over the temperature range of 350-600 ℃ during the heating stage of the calcination process,but rather underwent a condensation reaction within the same temperature range to form carbon-containing species with a lower ratio of hydrogen to carbon and a higher condensation degree,which promoted the decomposition of sulfate to form SO2.Systematic experimental work revealed that three different measures,i.e.,applying the staged calcination method,reducing the heating rate,and increasing the air flow rate,during the calcination process could all achieve the effect of reducing SO2 emissions.
aluminasesbania powdercellulosesulfur dioxide
Hu Anpeng、Wang Zhen、Yang Qinghe、Hu Dawei、Gong Yu、Jia Yanzi、Dai Qiaoling、Pu Ning
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SINOPEC Research Institute of Petroleum Processing,Beijing 100083,China