首页|X射线光电子能谱(XPS)在无铅基陶瓷分析中的应用

X射线光电子能谱(XPS)在无铅基陶瓷分析中的应用

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无铅基陶瓷作为储能材料能够解决能源短缺问题而受广泛关注,在无铅基陶瓷的研究分析过程中,对于陶瓷材料的元素化学态分析是非常重要的.X射线光电子能谱(X-ray Photoelectron Spectroscopy,XPS)作为一种基于光电效应为原理能够精准捕获样品表面元素信息的分析技术,可以获得测试样的元素种类、元素化学态比值等关键信息,利用这些关键信息能够从陶瓷材料的机理方面分析性能提高的原因.对XPS在研究和改性无铅基陶瓷过程中的应用进行阐述,其中包括表征碱金属元素挥发现象和漏电流问题,及掺杂改性的机理分析和缺陷偶极子分析,为XPS在无铅基陶瓷分析中的研究工作提供帮助.
Application of X-ray Photoelectron Spectroscopy in Lead-free Ceramics
As energy storage materials,lead-free ceramics have attracted widespread attention for their ability to solve energy shortages.In theresearch and analysis of lead-free ceramics,it is crucial to analyze the chemical states of each element within the ceramic matrix.X-ray photoelectron spectroscopy(XPS)is an analytical technique that accurately captures elemental information from the surface of samples,based on the principle of the photoelectric effect,and provides crucial data including elemental composition and valence state distribution.And the key information could be used to analyze the reasons for the improved performance of ceramic materials from the perspective of their mechanisms.The application of XPS in the study and modification of lead-free ceramics was described,including the characterization of alkali metal volatilization,leakage current,mechanism analysis of doping modification,and defect dipoles.It aims to contribute to future research efforts in using XPS to analyze lead-free ceramics.

X-ray photoelectron spectroscopylead-free ceramicalkali metal volatilizationionic replacement

杨志朋、李仕敏、宋世杰、杨文超、湛永钟

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广西大学资源环境与材料学院,省部共建特色金属材料与组合结构全寿命安全国家重点实验室,有色金属及材料加工新技术教育部重点实验室,南宁 530004

X射线光电子能谱(XPS) 无铅基陶瓷 碱元素挥发 离子取代

2025

中国无机分析化学
北京矿冶研究总院

中国无机分析化学

北大核心
影响因子:1.306
ISSN:2095-1035
年,卷(期):2025.15(1)