中国物理快报(英文版)2024,Vol.41Issue(3) :140-145.DOI:10.1088/0256-307X/41/3/037305

Interstitial Doping of SnO2 Film with Li for Indium-Free Transparent Conductor

陈兴谦 李昊臻 陈伟 梅增霞 Alexander Azarov Andrej Kuznetsov 杜小龙
中国物理快报(英文版)2024,Vol.41Issue(3) :140-145.DOI:10.1088/0256-307X/41/3/037305

Interstitial Doping of SnO2 Film with Li for Indium-Free Transparent Conductor

陈兴谦 1李昊臻 1陈伟 2梅增霞 3Alexander Azarov 4Andrej Kuznetsov 4杜小龙5
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作者信息

  • 1. Beijing National Laboratory for Condensed Matter Physics,and Institute of Physics,Chinese Academy of Sciences,Beijing 100190,China;Songshan Lake Materials Laboratory,Dongguan 523808,China;School of Physical Sciences,University of Chinese Academy of Sciences,Beijing 100049,China
  • 2. Songshan Lake Materials Laboratory,Dongguan 523808,China;Guangdong SinoPrime Technology Co.,Ltd.,Dongguan 523808,China
  • 3. Beijing National Laboratory for Condensed Matter Physics,and Institute of Physics,Chinese Academy of Sciences,Beijing 100190,China;Songshan Lake Materials Laboratory,Dongguan 523808,China
  • 4. Department of Physics,Centre for Materials Science and Nanotechnology,University of Oslo,P.O.Box 1048,Blindern,N-0316 Oslo,Norway
  • 5. Beijing National Laboratory for Condensed Matter Physics,and Institute of Physics,Chinese Academy of Sciences,Beijing 100190,China;Songshan Lake Materials Laboratory,Dongguan 523808,China;Guangdong SinoPrime Technology Co.,Ltd.,Dongguan 523808,China
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Abstract

SnO2 films exhibit significant potential as cost-effective and high electron mobility substitutes for In2O3 films.In this study,Li is incorporated into the interstitial site of the SnO2 lattice resulting in an exceptionally low resistivity of 2.028 × 10-3 Ω·cm along with a high carrier concentration of 1.398 × 1020 cm-3 and carrier mobility of 22.02 cm2/V·s.Intriguingly,Lii readily forms in amorphous structures but faces challenges in crystalline formations.Furthermore,it has been experimentally confirmed that Lii acts as a shallow donor in SnO2 with an ionization energy ΔED1 of-0.4 eV,indicating spontaneous occurrence of Lii ionization.

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基金项目

Key-Area Research and Development Program of Guangdong Province(2021B0101260001)

Guangdong Basic and Applied Basic Research Foundation(2019A1515110411)

INT-PART Program at the Research Council of Norway(322382)

出版年

2024
中国物理快报(英文版)
中国科学院物理研究所,中国物理学会

中国物理快报(英文版)

CSTPCDCSCDEI
影响因子:0.515
ISSN:0256-307X
参考文献量23
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