中国钨业2024,Vol.39Issue(2) :46-52,69.DOI:10.3969/j.issn.1009-0622.2024.02.007

云南某白钨矿加温浮选尾矿再回收试验研究

Experimental Study on Rerecovery of Tailings from a Scheelite Heating Flotation in Yunnan Province

刘泽洪 白俊智 刘显华 李彬 李欢
中国钨业2024,Vol.39Issue(2) :46-52,69.DOI:10.3969/j.issn.1009-0622.2024.02.007

云南某白钨矿加温浮选尾矿再回收试验研究

Experimental Study on Rerecovery of Tailings from a Scheelite Heating Flotation in Yunnan Province

刘泽洪 1白俊智 2刘显华 1李彬 1李欢1
扫码查看

作者信息

  • 1. 文山麻栗坡紫金钨业集团有限公司,云南 文山 663600
  • 2. 文山麻栗坡紫金钨业集团有限公司,云南 文山 663600;紫金矿业集团股份有限公司,福建 上杭 364200
  • 折叠

摘要

云南某白钨矿采用常温粗选、加温精选的浮选工艺,目前该白钨矿加温精选尾矿WO3品位达到0.27%,因此对该加温浮选尾矿进行浮选回收钨金属试验研究具有经济意义.由于该加温浮选尾矿矿浆浓度偏低为10.20%,且在加温浮选作业过程经水玻璃高温、长时间搅拌,白钨矿受到强烈抑制,再浮选回收率低,精矿品位难以得到提升.经过探索试验研究,将加温浮选尾矿矿浆浓度预先浓缩到40%,添加500 g/t水玻璃、400 g/t氧化石蜡皂进行粗选,可获得粗精矿 WO3 品位为 1.741%,回收率为 73.09%的粗选指标.选出的粗精矿经添加高效组合抑制剂(水玻璃 15 000 g/t+高效抑制剂 BTF 15 000 g/t)进行常温一粗三精的开路精选试验,可获得精矿 WO3 品位为11.65%、回收率为43.86%的精选指标.最终闭路试验流程为:加温浮选尾矿经过一次粗选二次扫选得到粗精矿后,经一次粗精选三次精选,可获得钨精矿WO3品位为10.52%、回收率为51.79%的选矿指标.

Abstract

A scheelite mine in Yunnan province adopts a flotation process involving rougher flotation at room temperature followed by cleaner flotation at elevated temperatures.Currently,the grade of the tailings from heated flotation reaches 0.27%,making it economically viable to conduct tests on the flotation recovery of tungsten from these tailings.Due to the low concentration(10.2%)of the heated tailings,the strong inhibition of scheelite by high-temperature sodium silicate,and prolonged stirring during the heated flotation process,the recovery rate of re-flotation is low,and it is difficult to improve the concentrate grade.Through experimental exploration,the pulp concentration of the heated tailings is pre-concentrated to 40%.By adding 500 g/t sodium silicate and 400 g/t oxidized paraffin soap,a coarse concentrate grade of 1.741%and a recovery rate of 73.09%are achieved.A high-efficiency combination inhibitor(15,000 g/t sodium silicate+15,000 g/t BTF)is then used,and the selected rough concentrate underwent an open-circuit flotation test at room temperature,with one rougher stage and three cleaner stages,achieving a WO3 grade of 11.65%and a recovery rate of 43.86%.In the final closed-circuit process,following one rougher stage and two scavenger stages,the coarse concentrate is subjected to one rougher and three cleaner stages,resulting in a tungsten concentrate with a grade of 10.52%and a recovery rate of 51.79%.

关键词

尾矿浮选/矿浆预先浓缩/常温精选/高效组合抑制剂

Key words

re-flotation of heated tailings/preconcentration of pulp/select at room temperature/high efficiency combination inhibitor

引用本文复制引用

出版年

2024
中国钨业
中国钨业协会

中国钨业

CSTPCD
影响因子:0.57
ISSN:1009-0622
段落导航相关论文