The material preparation process exerts a considerable influence on the microstructure and properties of the material. Ni-W-Ti2AlC composite coatings were prepared via pulsed electro-deposition. The effects of current density,duty cycle,frequency,and addition of Ti2AlC on the microstructure and properties of the coatings were investigated through orthogonal experiments with the objective of determining the optimal processing parameters. The crystal structure,surface morphology,and coating thickness were characterised using field emission scanning electron microscopy (FE-SEM). The corrosion resistance and wear resistance of the coatings were evaluated through electrochemical testing and tribological tests. The results indicated that the optimal process parameters for the preparation of Ni-W-Ti2AlC composite coatings are a current density of 8 A/dm2,a frequency of 200 Hz,a duty cycle of 70%,and a Ti2AlC addition of 7.5 g/L.