首页|基于近红外光激发h-BN/Au纳米复合材料的恩诺沙星检测

基于近红外光激发h-BN/Au纳米复合材料的恩诺沙星检测

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食品中残留的恩诺沙星威胁着人类健康和环境安全,建立快速、灵敏的抗生素检测方法具有重要的生物安全价值.通过氙灯液相辐照方式,合成h-BN/Au纳米复合材料的近红外表面增强拉曼散射(NIR-SERS)基底,在近红外光(785nm)激发下,h-BN/Au纳米复合材料的NIR-SERS活性约是单金属Au纳米颗粒结构的2.4倍;在200℃高温条件下,约90%的NIR-SERS活性可以很好地保持7天;h-BN/Au纳米复合材料实现了对抗生素恩诺沙星(浓度范围:10-3~10-7 M)的检测,其NIR-SERS信号强度与浓度之间线性关系良好.基于h-BN/Au纳米复合材料实现探针分子恩诺沙星随温度的NIR-SERS实时监测,可为食药环中抗生素的定量检测提供实验依据.
Near Infrared Surface-enfanced Raman Scattering of h-BN/Au Nanocomposites at Enrofloxacin Detection
As the enrofloxacin vestigein food is a threat to human health and environmental safety,it is important to establish rapid and sensitive antibiotic detections for it.The h-BN/Au nanocomposite was successfully synthesized by xenon lamp irradiation in liquid phase,realizing the low concentration detection of dye molecule crystal violet(CV)(10-12 M),and meeting the ultra-sensitive requirement of the trace detection of NIR-SERS.The experimental results showed that the NIR-SERS activity of h-BN/Au nanocomposites was about 2.4 times that of Au nanoparticles under 785nm excited.At the same time,under the high temperature condition of 200℃,~90%of the NIR-SERS activity can be maintained for 7 days.The h-BN/Au nanocomposite realized the detection of the concentration of Enrofloxacin(10-3M~10-7 M),and its NIR-SERS signal intensity showed a good linear relationship with the concentration.The results showed that real-time monitoring of probe molecule enrofloxacin with temperature was realized based on h-BN/Au nanocomposite,which provides the experimental basis for quantitative detection of antibiotics in public security.

h-BN/Au nanocompositenear infraredsurface-enhanced Raman scatteringantibiotic detectionenrofloxacin

马慧

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山东警察学院公共基础教研部 山东 济南 250200

山东大学物理学院 山东 济南 250100

贵金属纳米复合材料 近红外光 表面增强拉曼散射 抗生素检测 恩诺沙星

2023年度山东警察学院科技计划项目

YKYPYZX202311

2024

中国刑警学院学报
中国刑警学院

中国刑警学院学报

影响因子:0.024
ISSN:
年,卷(期):2024.(1)
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