首页|Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles:A review

Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles:A review

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In this paper,the lanthanoid complexes of N5 and N6 macrocycle ligands,without pendant arms or additional heteroatoms,are surveyed.This review covers the period from 2015 to the current date,since in 2014 Schiff base macrocyclic ligands incorporating the pyridine moiety,and their complexes,were revised,and in 2015 the chemistry of pentaaza macrocycle ligands with rare earth metals was also summarized.Porphyrin and phthalocyanine ligands are not included in this review,which primarily focuses on complexes with Schiff bases and amines without pendant arms or any additional donor other than nitrogen.The synthetic methods,structural characterization,based on single X-ray crystal data,and properties of the lanthanoid complexes,with special attention to magneto-structural correlations,are presented herein.

LanthanoidN5,N6 macrocycleCoordination chemistryChiralityBiological activityMolecule magnet

Julio Corredoira-Vázquez、Cristina González-Barreira、Paula Oreiro-Martínez、Ana M.García-Deibe、Jesús Sanmartín-Matalobos、Matilde Fondo

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Departamento de Química Inorgánica,Facultade de Química,Universidade de Santiago de Compostela,Campus Vida,15782,Santiago de Compostela,Spain

Phantom-g,CICECO-Aveiro Institute of Materials,Department of Physics,University of Aveiro,3810-193,Aveiro,Portugal

Institute of Materials(iMATUS),Universidade de Santiago de Compostela,15782,Santiago de Compostela,Spain

J.C-V acknowledges Xunta de Galicia for his postdoctoral fellowship

ED481B-2022-068

2024

10.1016/j.jre.2023.03.013

稀土学报(英文版)
中国稀土学会

稀土学报(英文版)

CSTPCDEI
影响因子：1.3
ISSN：1002-0721
年,卷(期)：2024.42(1)
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