首页|铁水包脱磷工艺优化与工业试验

铁水包脱磷工艺优化与工业试验

扫码查看
随着优质矿产逐渐减少,低品质铁矿的使用使得脱磷任务加重,如何实现高效稳定的铁水预处理脱磷是炼钢技术研究者普遍关注的问题.采用工业数据分析、X射线荧光分析、直读光谱仪分析等方法,对某不锈钢厂铁水包脱磷工艺脱磷率、物料消耗、渣系成分进行分析;结合FactSage热力学计算、正交试验,炉渣矿相与成分分析等方法优化铁水包脱磷造渣供氧工艺,并进行工艺试验对比.结果表明,工艺优化前脱磷率低、不稳定,物料消耗偏多,炉渣流动性差,碱度偏低;通过增大氧气流量、调整辅料加入制度,优化后炉渣熔点降低、未熔石灰含量减少,炉渣形成了更多的Ca2SiO4(C2S)相,利于富磷相形成;终点脱磷渣的平均脱磷率为93.2%,较优化前提高了 5.7个百分点,炉渣的磷分配比(LP)增大,平均lg LP为4.11,较优化前提高了 23%.工艺优化后吨铁石灰消耗量减少4.37 kg,氧化铁皮消耗量减少5.12 kg,化渣剂消耗量减少0.54 kg,氧气消耗量增加0.73 m3,总体辅料消耗成本降低,符合高效稳定、绿色低碳生产,对钢铁企业提升自身产品竞争力具有重要意义.
Process optimization and industrial test of iron ladle dephosphorization
With the gradual reduction of high-quality minerals,the use of low-quality iron ore aggravates the dephos-phorization task.How to achieve efficient and stable dephosphorization of hot metal pretreatment is a common con-cern of steelmaking technology researchers.The dephosphorization rate,material consumption and slag composition of iron ladle dephosphorization process in a stainless steel plant were analyzed by industrial data analysis,X-ray fluo-rescence analysis and direct reading spectrograph analysis.Combined with FactSage thermodynamic calculation,or-thogonal test,slag mineral phase and composition analysis,the oxygen supply and slagging process of hot metal was optimized,and the process test was compared.The results show that before the process optimization,the dephos-phorization rate was low and unstable,the material consumption was too much,the slag fluidity was poor,and the basicity was low.By increasing the oxygen flow rate and adjusting the addition system of slag materials,the melting point of the slag and the content of unmelted lime decrease after optimization,and more Ca2SiO4(C2S)phase is formed in the slag,which is beneficial to the formation of phosphorus-rich phase.The average dephosphorization rate of the end-point dephosphorization slag is 93.2%,which is 5.7 percentage points higher than that before opti-mization,the phosphorus distribution ratio of slag(LP)increases,the average lg LP is 4.11,which is 23%higher than that before optimization.After the process optimization,the lime consumption per ton of iron is decreased by 4.37 kg,the oxide scale consumption per ton of iron is decreased by 5.12 kg,the slagging agent consumption per ton of iron is decreased by 0.54 kg,the oxygen consumption per ton of iron is increased by 0.73 m3,and the overall consumption cost of slag materials is decreased.It is in line with efficient,stable,green and low-carbon production,which is of great significance for steel plants to enhance their product competitiveness.

iron ladle dephosphorizationprocess optimizationindustrial testphase of slagmaterial consumption

冯梦龙、林路、姚同路、李相臣、何赛

展开 >

钢铁研究总院有限公司冶金工艺研究所,北京 100081

铁水包脱磷 工艺优化 工业试验 炉渣物相 物料消耗

国家自然科学基金资助项目国家自然科学基金资助项目国家自然科学基金资助项目

517040805187410252074093

2024

中国冶金
中国金属学会

中国冶金

CSTPCD北大核心
影响因子:0.907
ISSN:1006-9356
年,卷(期):2024.34(2)
  • 13