首页|海工用高氮钢螺栓的制备及其组织性能分析

海工用高氮钢螺栓的制备及其组织性能分析

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海工用螺栓长时间浸泡在海水中,要求其强度高、屈强比低、耐蚀性好.设计制备了一种低成本节镍型的高氮钢螺栓,通过组织观察、XRD检测、力学性能试验、化学浸泡腐蚀试验和动电位极化曲线测试,并与海工常用的316不锈钢螺栓进行对比分析.研究结果表明,本试验螺栓微观组织为奥氏体组织,且组织中含有大量孪晶并伴有少量第二相氮化物析出;试验螺栓抗拉强度为877 MPa、屈服强度为690 MPa、断后伸长量为7.3 mm、屈强比为0.79,该螺栓在抗拉强度不低于316螺栓的条件下,屈强比为其的84%,断后伸长量是其的2.16倍,力学性能明显优于316不锈钢螺栓,满足奥氏体不锈钢螺栓80等级要求.在质量分数为6%的FeCl3溶液中浸泡15 d的腐蚀试验表明,试验螺栓腐蚀失重率为0.051%,是316不锈钢螺栓腐蚀失重率0.132%的38.6%;动电位极化曲线结果显示,试验螺栓相较于316不锈钢螺栓自腐蚀电位更正,腐蚀电流密度更小,耐局部腐蚀性能更优异.综上,试验高氮钢螺栓成本低,力学性能和耐点蚀、耐局部腐蚀性能均优于316不锈钢螺栓,研究结果为海洋工程用高强螺栓新材料提供了理论依据和数据支撑.
Preparation and microstructure properties analysis of high nitrogen steel bolts for marine engineering
The bolts used in marine engineering are immersed in seawater for a long time,which requires high strength,low yield ratio and good corrosion resistance.A low-cost nickel-saving high nitrogen steel bolt was de-signed and prepared.The microstructure observation,XRD detection,mechanical properties test,immersion corro-sion test and potentiodynamic polarization curve test were carried out and compared with 316 stainless steel bolts commonly used in marine engineering.The results show that microstructure of the bolts in this test is austenite,and the microstructure contains a large number of twins and a small amount of second phase nitride precipitation.The tensile strength of test bolts is 877 MPa,the yield strength is 690 MPa,the elongation after fracture is 7.3 mm,and the yield ratio is 0.79.Under the condition that the tensile strength of test bolts is not lower than 316 stainless steel bolts,the yield ratio and the elongation after fracture of test bolts is 84%and 2.16 times of that of 316 stain-less steel bolts,respectively.The mechanical properties are obviously better than those of 316 stainless steel bolts,which meet the requirements of 80 grade austenitic stainless steel bolts.The corrosion test of bolts immersed in 6%FeCl3 solution for 15 d shows that the corrosion weight loss ratio of the test bolts is 0.051%,which is 38.6%of the corrosion weight loss ratio(0.132%)of 316 stainless steel bolts.The results of potentiodynamic polarization curves show that the self-corrosion potential of the test bolts is more positive than that of 316 stainless steel bolts,the cor-rosion current density is smaller,and the local corrosion resistance is better.In summary,the high nitrogen steel bolts in the test has lower cost and better mechanical properties,pitting corrosion resistance and local corrosion re-sistance than 316 stainless steel bolts.This study provides a theoretical basis and data support for new materials of high strength bolts for marine engineering.

high nitrogen steel boltmechanical propertycorrosion resistanceweight loss ratepolarization curve

刘吉猛、王书桓、赵定国、李皓、曹凯琪

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华北理工大学冶金与能源学院,河北唐山 063210

唐山市特种冶金及材料制备重点实验室,河北唐山 063210

高氮钢螺栓 力学性能 耐腐蚀 失重率 极化曲线

河北省高等学校基本科研业务项目河北省省级科技计划国家自然科学基金

JQN202201020311003D52274336

2024

中国冶金
中国金属学会

中国冶金

CSTPCD北大核心
影响因子:0.907
ISSN:1006-9356
年,卷(期):2024.34(3)
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