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稀土对HRB400E热轧钢筋连铸坯夹杂物的影响

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为了探究稀土对HRB400E钢中非金属夹杂物的影响,采用扫描电镜(SEM)、夹杂物自动分析系统(OTS)对不加稀土连铸坯(S质量分数0.023%,O质量分数0.006%)和加稀土连铸坯(S质量分数0.027%,O质量分数0.011%,La+Ce质量分数0.020 6%)中的夹杂物进行了对比分析.结果表明,加入稀土后硫化锰类(MnS)夹杂物数量所占比例约70%,变化不大,主要改性了二氧化硅-硫化锰类(SiO2-MnS)、硅酸盐类(Silicate)和硅酸盐-硫化锰类(Silicate-MnS)夹杂物,使其比例分别从18.46%下降到2.86%,5.54%下降到0.40%和4.00%下降到1.15%,并生成了稀土复合氧化物-硫化锰类(REO-Oxide-MnS)、稀土复合氧化物类(REO-Oxide)等稀土夹杂物,所占比例分别为15.78%和5.88%.加入稀土后粒径为[1,10]μm夹杂物密度上升,粒径大于10μm的夹杂物密度下降,夹杂物总体密度从154个/mm2上升到170个/mm2,平均尺寸从2.52μm略微上升到2.63 μm,变化不明显.稀土的添加将最大尺寸夹杂物出现的位置从距内弧1/4处转移到中心,连铸坯上MnS和Silicate-MnS密度从边部到中心减少的趋势没有改变,而SiO2-MnS、Silicate类夹杂物密度的变化趋势由从边部到中心减少变为增加,生成的稀土夹杂物密度从边部到中心先增加后减少.研究结果为利用稀土调控钢中夹杂物提供了依据.
Influence of rare earth elements on inclusions of HRB400E hot-rolled rebar billet
In order to explore the effect of rare earth on non-metallic inclusions in HRB400E steel,scanning electron microscope(SEM)and automatic inclusion analysis system(OTS)were used to compare and analyze the inclusions in the continuous casting billet without rare earth(w(S)is 0.023%,w(O)is 0.006%)and with rare earth(w(S)is 0.027%,w(O)is 0.011%,w(La+Ce)is 0.020 6%).The results show that after the addition of rare earth,the proportion of manganese sulfide(MnS)inclusions is about 70%,and there is little change.Silica-manganese sulfide(SiO2-MnS),silicate(Silicate)and silicate-manganese sulfide(Silicate-MnS)are mainly modified,and the proportion is reduced from 18.46%to 2.86%,5.54%to 0.40%and 4.00%to 1.15%,respectively.Rare earth inclusions such as rare earth composite oxide-manganese sulfide(REO-Oxide-MnS)and rare earth composite oxides(REO-Oxide)are formed,accounting for 15.78%and 5.88%,respectively.With the addition of rare earth ele-ments,the density of inclusions with particle size of[1,10]μm increases,while the density of inclusions with parti-cle size greater than 10 μm decreases,the overall inclusion density increases from 154 pieces/mm2 to 170 pieces/mm2,and the average size increases slightly from 2.52 μm to 2.63 μm.With the addition of rare earth elements,the position of the maximum size inclusion is transferred from one-fourth of the distance from the arc to the center,the decreasing trend of MnS and Silicate-MnS density from edge to center on continuous casting billet is not changed,while the decreasing trend of SiO2-MnS and silicate inclusion density from edge to center is changed to in-creasing trend,and the density of rare earth inclusion increases at first and then decreases from edge to center.The study results provide a basis for controlling inclusions in steel with rare earth.

non-metallic inclusionsrare earth elementscontinuous casting billetrebarautomatic SEM-EDS analysis

陆晓杰、李健、陆恒昌、杨边疆、徐德祥、董瀚

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上海大学材料科学与工程学院,上海 201800

陕钢集团产业创新研究院有限公司,陕西汉中 723000

上海大学(浙江)高端装备基础件材料研究院,浙江嘉兴 314000

上海大学新材料(泰州)研究院,江苏泰州 225500

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非金属夹杂物 稀土元素 连铸坯 螺纹钢 自动扫描电镜分析

河北省重点研发计划

20311009D

2024

中国冶金
中国金属学会

中国冶金

CSTPCD北大核心
影响因子:0.907
ISSN:1006-9356
年,卷(期):2024.34(4)
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