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高强度生物质含碳球团制备及性能优化

Preparation and performance optimization for biomass carbon-bearing pellets with high strength

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炼铁原料劣化趋势难以改变,含碳球团为低碳冶炼提供了可能.将生物质作为清洁可再生零碳排放碳源、用于制备含碳球团还原剂成为钢铁企业节能降碳生产的发展趋势之一.目前限制含碳球团应用的关键因素是其高温强度较差,研究如何提高含碳球团高温强度具有重要意义.为此,采用大石河粉为含铁原料、生物质热解炭为还原剂,探究成型压力、水分添加量、焙烧制度及黏结剂种类对含碳球团的影响.结果表明,含碳球团强度随着成型压力和水分添加量增加均先升高后降低,以16 MPa成型压力和8%水分添加量为宜.随着还原温度升高,生物质含碳球团强度先降低后升高,由于在900~1 000 ℃温度区间发生晶格畸变,导致体积膨胀,强度最差;后期随着温度升高,金属铁逐渐汇聚成片,强度和金属化率均逐渐升高,1 200 ℃下金属化率可达84.84%.使用膨润土、水玻璃作为黏结剂时,常温强度较差,通过提高两者添加量可在一定程度上提升高温强度,但水玻璃含碱金属钠,不利于高炉顺行;使用标准水泥作为黏结剂时,常温和高温强度均较差,且生产效率较低;使用有机黏结剂CMC常温强度较高,但其在高温下易分解,球团高温强度较差;使用复合黏结剂可以同时获得常温和高温强度,可通过调节配加量满足不同炉窑对炉料的要求.
As the deterioration trend of ironmaking raw materials is difficult to change,carbon-bearing pellets pro-vide the possibility for low-carbon ironmaking.Using biomass as a clean and renewable carbon source with zero-car-bon emission for the preparation of carbon-bearing pellets reductants has become one of the development trends for energy-saving and carbon-reducing production in iron and steel enterprises.Nowadays the key factor limiting the ap-plication of carbon-bearing pellets is their poor high temperature strength,so it is of great significance to study how to improve the high temperature strength of carbon-bearing pellets.Therefore,the effects of molding pressure,wa-ter addition,roasting system and binder types on the biomass carbon-bearing pellets were investigated using Dashihe powder as iron-containing raw material and biomass pyrolysis carbon as reductant.The results show that the strength of carbon-bearing pellets first increases and then decreases with the increase of molding pressure and water addition,and the optimum value is 16 MPa for molding pressure and 8%for water addition.With the increase of re-duction temperature,the strength of biomass carbon-bearing pellets decreases first and then increases,and 900-1 000 ℃ is the temperature range with the weakest strength due to the volume expansion caused by lattice distor-tion.In the later stage,with the increase of temperature,the metal iron gradually converges into sheets,and the strength and metallization rate are gradually increases.The metallization rate can reach 84.84%at 1 200 ℃.When using bentonite and sodium silicate as the binder,the strength is poor at normal temperature,and the high tempera-ture strength can be improved to a certain extent by increasing the binder addition amount.But the sodium silicate contains alkali metal Na,which is not conducive to the blast furnace.When using standard cement as the binder,the strength at normal temperature and high temperature are both poor,and the production efficiency is low.The strength of organic binder CMC is high at normal temperature,but it is easy to decompose at high temperature,and the pellets strength is poor at high temperature.The strength at normal temperature and high temperature can be obtained at the same time by composite binder,and the requirements of raw materials for different furnaces can be meet by adjusting the addition.

biomasscarbon peak-carbon neutralhigh strength carbon-bearing pelletsbinderhigh temperature strength

赵满祥、刘嘉雯、贾国利、王广伟、余晓波

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北京首钢股份有限公司迁顺技术中心,北京 100041

北京科技大学冶金与生态工程学院,北京 100083

生物质 双碳 高强度含碳球团 黏结剂 高温强度

国家自然科学基金国家自然科学基金

5207402952174295

2024

中国冶金
中国金属学会

中国冶金

CSTPCD北大核心
影响因子:0.907
ISSN:1006-9356
年,卷(期):2024.34(4)
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