首页|Er含量对Zn-Al-Mg合金组织和耐腐蚀性能的影响

Er含量对Zn-Al-Mg合金组织和耐腐蚀性能的影响

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为了研究Er元素的添加对Zn-Al-Mg合金微观组织和腐蚀性能的影响,分别熔炼了 4种不同成分的合金,即 Zn-1.7%Al-1.1%Mg-0.1%Er、Zn-1.7%Al-1.1%Mg-0.5%Er、Zn-7%Al-2%Mg-0.1%Er 和 Zn-7%Al-2%Mg-0.5%Er.通过SEM观察合金的组织和析出相,采用EDS分析不同组织和相的成分,并利用XRD检测确定析出相的比例.通过EPMA分析,研究Er2Zn17在不同成分四元合金中的面积分数以及分布规律.测试了 Tafel曲线和Nyquist曲线,以研究不同成分合金的耐腐蚀性能.结果显示,Zn-1.7%Al-1.1%Mg-0.5%Er合金比Zn-1.7%Al-1.1%Mg-0.1%Er 合金的腐蚀电流密度低,Zn-7%Al-2%Mg-0.5%Er 合金比 Zn-7%Al-2%Mg-0.1%Er合金的腐蚀电流密度低,说明随着Er含量的增加,合金的耐腐蚀性能进一步提高.最终结果表明,Er元素的添加可以细化合金的组织,提高合金的耐腐蚀性能.
Influence of Er content on microstructure and corrosion resistance of Zn-Al-Mg alloys
In order to study the effect of Er element addition on the microstructure and corrosion resistance of Zn-Al-Mg alloy,four kinds of alloys with different compositions were melted separately,namely Zn-1.7%A1-1.1%Mg-0.1%Er,Zn-1.7%Al-1.1%Mg-0.5%Er,Zn-7%Al-2%Mg-0.1%Er,and Zn-7%Al-2%Mg-0.5%Er.The micro-structure and precipitated phase of the alloys were observed by SEM.The composition of different microstructures and phases was analyzed by EDS,and the proportion of precipitated phases was determined by XRD.The area frac-tion and distribution of Er2Zn17 in quaternary alloys with different compositions were studied by EPMA analysis.The Tafel curve and Nyquist curve were tested to study the corrosion resistance of alloys with different composi-tions.The results show that the corrosion current density of Zn-1.7%Al-1.1%Mg-0.5%Er alloy is lower than that of Zn-1.7%Al-1.1%Mg-0.1%Er alloy,and the corrosion current density of Zn-7%Al-2%Mg-0.5%Er alloy is low-er than that of Zn-7%Al-2%Mg-0.1%Er,indicating that the corrosion resistance of the alloy is further improved with the increase of Er content.The final results indicate that the addition of Er element can refine the microstruc-ture of the alloy and improve its corrosion resistance

Er added Zn-Al-Mg quaternary alloysolidified microstructurecorrosion resistanceEr2Zn17self-cor-rosion current

刘广会、徐呈亮、滕华湘、蒋光锐、刘全利、陈建军

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首钢集团有限公司技术研究院,北京 100043

含Er锌铝镁合金 凝固组织 耐腐蚀性 Er2Zn17 自腐蚀电流

河北省重大科技成果转化专项

22281001Z

2024

中国冶金
中国金属学会

中国冶金

CSTPCD北大核心
影响因子:0.907
ISSN:1006-9356
年,卷(期):2024.34(7)
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