首页|Cr12MoV钢铸坯碳化物解析

Cr12MoV钢铸坯碳化物解析

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Cr12MoV钢是应用最广泛的冷作模具钢,属于高铬高碳莱氏体钢,钢中碳化物的形态、数量、大小和分布对Cr12MoV钢的性能有重要影响.采用金相显微镜、扫描电镜、夹杂物三维腐刻装置、X射线衍射仪和能谱分析仪对某厂生产的Cr12MoV模铸坯中碳化物类型、形态及分布情况进行解析,使用Thermo-Calc 2020b计算Cr12MoV冷作模具钢的相转变和碳化物析出行为.结果表明,Cr12MoV冷作模具钢碳化物类型为富铬富铁的M7C3型碳化物和M23C6型碳化物,M7C3型碳化物所含主要元素为铬、铁、碳、钼,M23C6型碳化物所含主要元素为铁、铬、钼、碳.铸坯中碳化物形貌主要可以分为4类,颗粒状碳化物、块状碳化物、棒状碳化物、网状碳化物.颗粒状碳化物尺寸为2~5 μm,块状碳化物尺寸为10~15 μm,棒状碳化物尺寸为30~40 μm,网状碳化物由颗粒状、块状、棒状碳化物聚集形成,其尺寸达80 μm.从边部到芯部碳化物形态的演变规律为颗粒状→块状→棒状→网状,边部到芯部碳化物不均匀性逐渐增强,边部碳化物呈颗粒状弥散分布,1/4处碳化物呈长棒状,芯部碳化物偏聚成网状;铸坯从边部到芯部,碳化物的平均等效直径由边部的5.7μm增加到芯部的8.5μm,碳化物面积比例由边部的8.2%增长到芯部的9.5%,碳化物的密度由边部的2 961个/mm2下降到芯部的1 189个/mm2.通过解析Cr12MoV钢铸坯中碳化物的类型、形态与分布,寻找碳化物在铸坯中的分布规律,为工厂调控钢中碳化物形态、优化钢的性能提供理论依据.
Analysis of carbide in Cr12MoV steel billet
Cr12MoV steel is the most widely used cold work die steel,which belongs to high chromium and high car-bon lesteritic steel,and the form,quantity,size and distribution of carbides in the steel have an important impact on the properties of Cr12MoV steel.Metallographic microscope,scanning electron microscope,three-dimensional cor-rosion engraving device for inclusions,X-ray diffractometer and energy dispersive analyzer were used to analyze the type,morphology and distribution of carbides in Cr12MoV die casting billets in a factory,and the phase transition and carbide precipitation behavior of Cr12MoV cold work die steel were calculated by Thermo-Calc 2020b.The re-sults show that the carbide types of Cr12MoV cold work die steel are chromium-rich and iron-rich M7C3 carbides and M23C6 carbides,the main elements of M7C3 carbides are chromium,iron,carbon and molybdenum,and the main el-ements of M23C6 carbides are iron,chromium,molybdenum and carbon.The carbide morphology in the casting bil-let can be mainly divided into four categories,granular carbide,bulky carbide,rod-like carbide,and reticulated car-bide.The size of granular carbide is 2-5 μm,the size of bulk carbide is 10-15 μm,the size of rod carbide is 30-40μm,and the reticulated carbide is formed by the aggregation of granular,bulky and rod-like carbides and its size is up to 80 μm.The evolution of carbide morphology from edge to core is as follows,granular → blocky→ rod-like reticulated,the heterogeneity of carbide from edge to core is gradually enhanced,and the carbide at the edge is dis-tributed in a granular manner,the carbides at 1/4 are long rod-shaped,and the carbides in core are segregated into a network.From edge to core,the average equivalent diameter of carbide increases from 5.7 μm at the edge to 8.5 μm at the core,the proportion of carbide area increases from 8.2%to 9.5%from the core,and the density of carbide decreases from 2 961/mm2 at the edge to 1 189/mm2 at the core.By analyzing the type,morphology and distribution of carbides in Cr12MoV steel billets,the distribution law of carbides in the casting billets is found,which provides a theoretical basis for the factory to regulate the carbide morphology in the steel and optimize the performance of steel.

Cr12MoVcold work die steeldie casting billetcarbidethree-dimensional engraving

郑鹏、刘松涛、徐翔宇、刘斌、付建勋

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上海大学材料科学与工程学院先进凝固技术中心,省部共建高品质特殊钢冶金与制备国家重点实验室,上海 200444

鞍钢集团北京研究院有限公司,北京 102200

Cr12MoV 冷作模具钢 模铸坯 碳化物 三维腐刻

国家自然科学基金资助项目

52074179

2024

中国冶金
中国金属学会

中国冶金

CSTPCD北大核心
影响因子:0.907
ISSN:1006-9356
年,卷(期):2024.34(9)
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