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油菜秸秆木塑复合材料的制备研究

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为解决油菜秸秆处理困难的问题,以油菜秸秆为原料,采用混炼热压工艺制备木塑复合材料,系统研究了油菜秸秆的填充量、粒径和聚合物种类对木塑复合材料性能的影响,并将其与GB/T 24137-2009《木塑装饰板》中相关指标进行比较.研究结果显示,当油菜秸秆的填充量为30%、粒径为80目时,木塑复合材料性能指标较优;聚丙烯(PP)制备的复合材料性能优于乙烯-丙烯酸乙酯共聚物(EAA)、高密度聚乙烯(HDPE)和聚氯乙烯(PVC)制备的复合材料;比较了稻壳灰、亲水型纳米SiO2和亲油型纳米SiO2对材料性能指标的影响,结果表明添加5%的亲油型纳米SiO2或5%的稻壳灰能有效增强复合材料性能,拉伸强度分别提高了2.01%和11.25%、弯曲强度分别提高了12.73%和7.32%、弹性模量分别提高了7.13%和6.43%.25%油菜秸秆粉、5%稻壳灰和70%PP制备得到的木塑复合材料性能最优:拉伸强度17.83±0.56 MPa、弯曲强度33.68±0.04 MPa、弹性模量2119.32±6.39 MPa、邵氏硬度72.30±1.09 HD、含水率0.39±0.02%、吸水厚度膨胀率0.58±0.00%,基本符合国家标准.
Research on preparation of rapeseed straw wood-plastic composites
To address the rapeseed straw processing,wood-plastic composites were prepared by mixing and hot-pressing process using rapeseed straw as raw material.Effects of filling amount,particle size and polymer types of rapeseed straw on performance indexes of wood-plastic composites were systematically studied,and were com-pared with relevant indexes in GB/T 24137-2009.Results showed that properties of wood-plastic composites were better,when filling amount of rapeseed straw was 30%and the particle size was 80 mesh.Performance of compos-ites prepared by polypropylene was better than that of ethylene-acrylic acid copolymer,high density polyethylene and polyvinyl chloride.The effects of rice husk ash,hydrophilic nano-silica and hydrophobic nano-silica on perfor-mance indexes of materials were compared.It indicated that adding 5%oleophilic nano-silica or 5%rice husk ash could effectively enhance the performance of composites,with tensile strength increased by 2.01%and 11.25%,bending strength increased by 12.73%and 7.32%,and elastic modulus increased by 7.13%and 6.43%,respective-ly.The wood-plastic composites prepared with a formula of 25%rapeseed straw powder,5%rice husk ash and 70%polypropylene had the best performance as tensile strength 17.83±0.56 MPa,bending strength 33.68±0.04 MPa,elastic modulus 2119.32±6.39 MPa,shore hardness 72.30±1.09 HD,water content 0.39±0.02%,and water absorp-tion thickness expansion rate 0.58±0.00%.These performances were basically met the national standards.

rapeseed strawwood-plastic compositespolypropylenemechanical properties

吴亦珺、张蓉蓉、肖婧怡、张维农、从艳霞

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武汉轻工大学食品科学与工程学院,湖北 武汉,430023

农产品加工与转化湖北省重点实验室,湖北 武汉,430023

大宗粮油精深加工教育部重点实验室,湖北 武汉,430023

油菜秸秆 木塑复合材料 聚丙烯 力学性能

2025

中国油料作物学报
中国农业科学院油料作物研究所

中国油料作物学报

北大核心
影响因子:1.296
ISSN:1007-9084
年,卷(期):2025.47(2)