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金属离子在矿物浮选中的典型作用

Typical roles of metal ions in mineral flotation: A review

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在矿物浮选中,金属离子可以通过选择性活化或抑制矿物表面,从而发挥重要的作用.尽管此前大量工作报道了金属离子在浮选中的作用,但大多仅是针对某一特定类型金属离子或目的矿物进行研究分析,缺乏一个全面的综述.本文对金属离子在矿物浮选中的影响因素进行详细分类,总结金属离子在不同种类矿物浮选中的作用机理.此外,还对常见探索作用机理的研究方法,包括经典的浮选、接触角测量、动电位测量,以及近年来流行的模拟计算、溶液化学计算和循环伏安等,进行梳理和分析.本文全面综述了金属离子在矿物浮选中的作用,发现金属离子的添加与去除、溶液化学环境改变、浮选药剂的选择等都可调控金属离子对矿物浮选的影响,对于精确调控矿物浮选具有重要指导意义.
In flotation, metal ions possess significant roles that are usually fulfilled by either selectively activating or depressing the target minerals. Despite that tremendous efforts have been made to address the roles of metal ions in flotation, it still lacks a comprehensive review, especially to compare various ions instead of focusing on a specific one. This review begins by elaborately categorizing the factors involved in affecting the roles of metal ions in flotation. After that, well-accepted mechanisms are updated and discussed from the ore type. Furthermore, typical approaches to explore the underlying mechanisms are emphasized, including traditional techniques such as micro-flotation, contact angle measurement, zeta potential measurement, and other recent prevailing methodologies, like computational method, solution chemistry calculation, and cyclic voltammetry. This work will pave the way to promote flotations via activities like selectively adding/reducing metal ions, choosing reagents, and regulating the slurry chemistry.

metal ionsflotationoxide mineralsilicate mineralsulfide mineral

高志勇、江哲伊、孙伟、高跃升

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中南大学 资源加工与生物工程学院,长沙 410083

中南大学 战略含钙矿物资源清洁高效利用湖南省重点实验室,长沙 410083

Department of Chemical Engineering, Michigan Technological University, Houghton 49931, United States

金属离子 浮选 氧化矿 硅酸盐矿 硫化矿

U2067201517743282021YFE01068002020JJ20442018RS3011B14034

2021

中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCDCSCDSCI
影响因子:1.183
ISSN:1003-6326
年,卷(期):2021.31(7)
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