首页|超音速火焰喷涂与激光重熔Al0.2CrFeNi(Co,Cu)合金的干滑动磨损及氧化性能对比研究

超音速火焰喷涂与激光重熔Al0.2CrFeNi(Co,Cu)合金的干滑动磨损及氧化性能对比研究

Comparative study on dry sliding wear and oxidation performance of HVOF and laser re-melted Al0.2CrFeNi(Co,Cu) alloys

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用超音速火焰喷涂(HVOF)法在316L不锈钢基体上沉积Al0.2CrFeNiCo和Al0.2CrFeNiCu两种高熵合金涂层,然后对涂层进行激光重熔(LR)以改善其显微组织.研究LR工艺对涂层干滑动磨损和氧化行为的影响.结果表明,将粉末与单体元素混合导致HVOF涂层中形成内氧化物.LR消除了氧化物和气孔.LR后,两种合金中均以FCC相为主,而在Al0.2CrFeNiCo合金中观察到BCC、sigma和Cr2O3相.HVOF后,Al0.2CrFeNiCo和Al0.2CrFeNiCu涂层的硬度分别为HV 591和HV 361.LR后,其硬度分别减小到HV 259和HV 270.与其他样品相比,虽然HVOF涂层受载荷增加的影响最大,但其表现出最高的耐磨性,且基体的耐磨性最差.氧化实验后,HVOF涂层被完全氧化,氧化50 h后涂层因其多孔结构从基体上脱落.LR涂层具有较好的抗氧化性能.氧化实验后,Al0.2CrFeNiCo涂层主要由Cr2O3氧化层组成,Cr2O3氧化层在氧化实验后期的生长速度较慢,而Al0.2CrFeNiCu涂层则主要由尖晶石相组成.
Al0.2CrFeNiCo and Al0.2CrFeNiCu high entropy alloys were deposited with high velocity oxygen fuel (HVOF) on 316L substrate. Later, a laser re-melting (LR) process was applied to enhancing the coating microstructure. LR process effects on dry sliding wear and oxidation behaviors were investigated. The mixture of powders with free elements led to the formation of inner oxides in HVOF coatings. The oxide and porosity were eliminated using LR. After LR, FCC was the dominant phase in both alloys, while BCC, sigma and Cr2O3 phases were observed in Al0.2CrFeNiCo alloy. The hardnesses of the Al0.2CrFeNiCo and Al0.2CrFeNiCu coatings after HVOF were HV 591 and HV 361, respectively. After LR, the hardnesses decreased to HV 259 and HV 270, respectively. Although HVOF coatings were most affected by increased load, they showed the highest wear resistance compared to other samples. The lowest wear resistance could be seen in the substrate. After the oxidation tests, HVOF coating layer was completely oxidized and also, the coating layer was delaminated from the substrate after 50 h oxidation due to its porous structure. LR coatings exhibited better oxidation performance. Al0.2CrFeNiCo was dominantly composed of Cr2O3, exhibiting a slower-growing tendency at the end of the oxidation tests, while Al0.2CrFeNiCu was composed of spinel phases.

high entropy alloylaser re-meltingHVOFwearoxidation

Azmi ERDOGAN、Kadir Mert DOLEKER

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Department of Metallurgy and Materials Engineering, Faculty of Engineering Architecture and Design, Bartın University, Bartın, Turkey

Department of Metallurgy and Materials Engineering, Faculty of Engineering, Ondokuz Mayıs University, Samsun, Turkey

高熵合金 激光重熔 超音速火焰喷涂(HVOF) 磨损 氧化

2019-FEN-A-0122019-FEN-A-013

2021

中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCDCSCDSCI
影响因子:1.183
ISSN:1003-6326
年,卷(期):2021.31(8)
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