首页|锂辉石浮选尾矿低温烧结制备多孔陶瓷及其性能

锂辉石浮选尾矿低温烧结制备多孔陶瓷及其性能

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以锂辉石浮选尾矿(SFT)、高岭土和低熔点玻璃粉(LPG)为原料,通过过氧化氢(H2O2)发泡法制备多孔陶瓷.添加LPG以降低多孔陶瓷的烧结温度,添加高岭土使多孔陶瓷对亚甲基蓝具有吸附性.多孔陶瓷平均抗折强度、抗压强度、显气孔率、吸水率和亚甲基蓝最大吸附量分别为5.60 MPa、4.66 MPa、52.27%、44.32%和0.7 mg/g.正交试验结果表明,烧结温度和H2O2用量分别对多孔陶瓷的力学性能和显气孔率有较大影响.随着烧结温度的升高,LPG逐渐软化,把矿物颗粒紧密地粘附在一起,这是多孔陶瓷力学性能提高的主要原因.高岭石在550℃时没有完全转化为偏高岭石,这可能是多孔陶瓷具有吸附性的主要原因.
Preparation and properties of porous ceramics from spodumene flotation tailings by low-temperature sintering
Porous ceramics were prepared with spodumene flotation talings (SFT), kaolin and low-melting point glass (LPG) powder, whose pores were formed by the chemical reaction of hydrogen peroxide (H2O2). LPG was used to reduce the sintering temperature of porous ceramics and kaolin was used to realize the adsorption to methylene blue (MB) of porous ceramics. The average flexural strength, compressive strength, apparent porosity, water absorption and maximum MB adsorption capacity were 5.60 MPa, 4.66 MPa, 52.27%, 44.32% and 0.7 mg/g, respectively. Moreover, the results of orthogonal experiments present that the sintering temperature and the dosage of H2O2 had great influence on the mechanical properties and apparent porosity of porous ceramics, respectively. The main reason for the improvement of mechanical properties of porous ceramics was that LPG gradually became soft with increasing the sintering temperature, which made the mineral particles adhere to each other closely. Kaolinite was not completely converted into metakaolin at 550 ℃, which might be the main reason why porous ceramics had adsorption properties.

spodumene flotation tailingsporous ceramicslow-temperature sinteringabsorption

杨洁、徐龙华、巫侯琴、金娇

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西南科技大学 固体废物处理与资源化教育部重点实验室,绵阳 621010

西南科技大学 环境友好能源材料国家重点实验室,绵阳 621010

西南科技大学 土木工程与建筑学院,绵阳 621010

长沙理工大学 交通运输工程学院,长沙 410114

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锂辉石浮选尾矿 多孔陶瓷 低温烧结 吸附

Nos.51674207519220912018QNRC001Nos.2019YFS04532018JY0148

2021

中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCDCSCDSCI
影响因子:1.183
ISSN:1003-6326
年,卷(期):2021.31(9)
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