Review of micro-scale and atomic-scale corrosion mechanisms of second phases in aluminum alloys
Localized corrosion of aluminum (Al) alloys, such as pitting corrosion, intergranular corrosion, and stress corrosion cracking is closely related to the micro-galvanic corrosion between the second phase and the Al matrix. Using high-resolution transmission electron microscopy and first principles calculations, the factors that affect corrosion mechanisms of the second phase in Al alloys at micro-scale and atomic-scale were examined, including the composition and structure of second phase, pH of the environment, stress and adsorption behavior of adsorbates (such as Cl−, H2O, OH− and O2−).
Al alloyscorrosiondealloyingfirst principles calculations
计元元、徐云泽、张斌斌、Yashar BEHNAMIAN、夏大海、胡文彬
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天津市材料复合与功能化重点实验室,天津 300350
天津大学 材料科学与工程学院,天津 300350
大连理工大学 船舶工程学院,大连 116024
中国科学院 海洋研究所 海洋环境腐蚀与生物污损重点实验室,青岛 266071
Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 2V4, Canada
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铝合金 腐蚀 脱合金化 第一性原理计算
authors are grateful for the financial support from the National Natural Science Foundation of China