首页|铝合金第二相腐蚀机理的微观/原子尺度研究进展

铝合金第二相腐蚀机理的微观/原子尺度研究进展

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铝合金的局部腐蚀(如点蚀、晶间腐蚀以及应力腐蚀开裂)与铝基体和第二相之间的微电偶腐蚀密切相关.采用高分辨率透射电子显微镜和第一性原理计算,从微观和原子尺度上分析影响铝合金第二相腐蚀机理的因素,包括第二相的组成与结构、环境的pH值、应力以及吸附物质(如Cl−,H2O,OH−和O2−)的吸附行为.
Review of micro-scale and atomic-scale corrosion mechanisms of second phases in aluminum alloys
Localized corrosion of aluminum (Al) alloys, such as pitting corrosion, intergranular corrosion, and stress corrosion cracking is closely related to the micro-galvanic corrosion between the second phase and the Al matrix. Using high-resolution transmission electron microscopy and first principles calculations, the factors that affect corrosion mechanisms of the second phase in Al alloys at micro-scale and atomic-scale were examined, including the composition and structure of second phase, pH of the environment, stress and adsorption behavior of adsorbates (such as Cl−, H2O, OH− and O2−).

Al alloyscorrosiondealloyingfirst principles calculations

计元元、徐云泽、张斌斌、Yashar BEHNAMIAN、夏大海、胡文彬

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天津市材料复合与功能化重点实验室,天津 300350

天津大学 材料科学与工程学院,天津 300350

大连理工大学 船舶工程学院,大连 116024

中国科学院 海洋研究所 海洋环境腐蚀与生物污损重点实验室,青岛 266071

Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 2V4, Canada

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铝合金 腐蚀 脱合金化 第一性原理计算

authors are grateful for the financial support from the National Natural Science Foundation of China

52171077

2021

中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCDCSCDSCI
影响因子:1.183
ISSN:1003-6326
年,卷(期):2021.31(11)
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