首页|时效处理对2195 Al-Li合金挤压型材腐蚀行为的影响

时效处理对2195 Al-Li合金挤压型材腐蚀行为的影响

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对2195铝锂合金分别进行欠时效(UA)、峰时效(PA)、双级时效(DA)和回归再时效(RRA)处理,观察并讨论其显微组织、晶间腐蚀(IGC)、剥落腐蚀(EXCO)和应力腐蚀开裂(SCC)行为.结果表明,合金经不同时效处理后,其IGC和EXCO耐蚀性顺序为:RRA>UA>DA>PA.PA和UA态的低耐蚀性主要是T1相在晶界处连续析出形成连续的腐蚀通道引起的,而粗大不连续析出的T1相以及较宽的无析出带导致的腐蚀通道中断是RRA态具有最佳耐蚀性的原因.RRA态合金表现出最好的抗应力腐蚀性能,抗应力腐蚀顺序为:RRA>DA>UA>PA.晶间Ti相的不连续析出促进了腐蚀裂纹穿过晶界进行扩展,从而提高了 2195铝锂合金的抗应力腐蚀性能.
Influence of aging treatment on corrosion behavior of extruded 2195 Al-Li alloy
The 2195 Al-Li alloy was processed by under-aging(UA),peak-aging(PA),double-aging(DA)and retrogression re-aging(RRA)treatments,and the microstructure,intergranular corrosion(IGC),exfoliation corrosion(EXCO)and stress corrosion cracking(SCC)behaviors were observed and discussed.The results show that the sequence of IGC and EXCO resistance is:RRA>UA>DA>PA.The low corrosion resistance of PA and UA is mainly caused by the continuous precipitation of Ti phases at grain boundaries to form continuous corrosion channels,while the interruption of corrosion channels caused by coarse and discontinuous T1 phases and wider precipitate free zone is the reason for the best corrosion resistance of RRA.The RRA alloy exhibits the best SCC resistance,and the order of SCC resistance is:RRA>DA>UA>PA.The discontinuous precipitation of intergranular T1 phases promotes the propagation of corrosion cracks across grain boundaries,thereby improving the SCC resistance.

agingmicrostructure evolutioncorrosion behaviorcorrosion mechanism

李辉、王志文、付绒、黄元春

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中南大学 机电工程学院,长沙 410083

中南大学高性能复杂制造国家重点实验室,长沙 410083

中南大学轻合金研究院,长沙 410083

时效 显微组织演变 腐蚀行为 腐蚀机理

国家自然科学基金

U1837207

2024

中国有色金属学报(英文版)
中国有色金属学会

中国有色金属学报(英文版)

CSTPCD
影响因子:1.183
ISSN:1003-6326
年,卷(期):2024.34(3)
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